Polymerization of styrene and methyl methacrylate in the presence of 2,2-diethyl-4,5,5-trimethyl-2,5-dihydroimidazol-1-oxyl

Polymerization of styrene and methyl methacrylate in the presence of 2,2-diethyl-4,5,5-trimethyl-2,5-dihydroimidazol-1-oxyl Full article

Journal

Polymer Science - Series B
ISSN: 1560-0904

Output data

Year: 2008, Volume: 50, Number: 11-12, Pages: 356-361 Pages count : 6 DOI: 10.1134/S1560090408110134

Authors

Pavlovskaya M.V. ¹ , Kirilyuk I.A. ² , Shchepalov A.A. ¹ , Grigoriev I.A. ² , Grishin D.F. ¹

Affiliations

1	(Данные Web of science) NI Lobachevskii State Univ, Inst Chem, Nizhnii Novgorod 603950, Russia
2	(Данные Web of science) Russian Acad Sci, Siberian Branch, Inst Organ Chem, Novosibirsk 603090, Russia

The polymerization of styrene and methyl methacrylate in the presence of 2,2-diethyl-4,5,5-trimethyl- 2,5-dihydroimidazol-1-oxyl has been studied. It has been demonstrated that the nitroxyl radical makes it possible to control chain propagation in the polymerization of styrene and to synthesize polymers with relatively low polydispersity coefficients (< 1.4). The polymerization of methyl methacrylate in the controlled mode cannot be performed because of the occurrence of a side reaction related to hydrogen atom transfer.

Pavlovskaya M.V. , Kirilyuk I.A. , Shchepalov A.A. , Grigoriev I.A. , Grishin D.F.
Polymerization of styrene and methyl methacrylate in the presence of 2,2-diethyl-4,5,5-trimethyl-2,5-dihydroimidazol-1-oxyl
Polymer Science - Series B. 2008. V.50. N11-12. P.356-361. DOI: 10.1134/S1560090408110134 WOS Scopus РИНЦ

Павловская М.В. , Кирилюк И.А. , Щепалов А.А. , Григорьев И.А. , Гришин Д.Ф.
Полимеризация стирола и метилметакрилата в присутствии 2,2-диэтил-4,5,5-триметил-2,5-дигидроимидазол-1-оксила
Высокомолекулярные соединения. Серия Б. 2008. Т.50. №12. С.2181-2187. РИНЦ

Published print:	Dec 1, 2008
Published online:	Dec 23, 2008

Web of science	WOS:000261959100013
Scopus	2-s2.0-59849083282
Elibrary	13572791
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