Polymerization of styrene and methyl methacrylate in the presence of 2,2-diethyl-4,5,5-trimethyl-2,5-dihydroimidazol-1-oxyl

Polymerization of styrene and methyl methacrylate in the presence of 2,2-diethyl-4,5,5-trimethyl-2,5-dihydroimidazol-1-oxyl Научная публикация

Журнал

Polymer Science - Series B
ISSN: 1560-0904

Вых. Данные

Год: 2008, Том: 50, Номер: 11-12, Страницы: 356-361 Страниц : 6 DOI: 10.1134/S1560090408110134

Авторы

Pavlovskaya M.V. ¹ , Kirilyuk I.A. ² , Shchepalov A.A. ¹ , Grigoriev I.A. ² , Grishin D.F. ¹

Организации

1	(Данные Web of science) NI Lobachevskii State Univ, Inst Chem, Nizhnii Novgorod 603950, Russia
2	(Данные Web of science) Russian Acad Sci, Siberian Branch, Inst Organ Chem, Novosibirsk 603090, Russia

The polymerization of styrene and methyl methacrylate in the presence of 2,2-diethyl-4,5,5-trimethyl- 2,5-dihydroimidazol-1-oxyl has been studied. It has been demonstrated that the nitroxyl radical makes it possible to control chain propagation in the polymerization of styrene and to synthesize polymers with relatively low polydispersity coefficients (< 1.4). The polymerization of methyl methacrylate in the controlled mode cannot be performed because of the occurrence of a side reaction related to hydrogen atom transfer.

Pavlovskaya M.V. , Kirilyuk I.A. , Shchepalov A.A. , Grigoriev I.A. , Grishin D.F.
Polymerization of styrene and methyl methacrylate in the presence of 2,2-diethyl-4,5,5-trimethyl-2,5-dihydroimidazol-1-oxyl
Polymer Science - Series B. 2008. V.50. N11-12. P.356-361. DOI: 10.1134/S1560090408110134 WOS Scopus РИНЦ

Павловская М.В. , Кирилюк И.А. , Щепалов А.А. , Григорьев И.А. , Гришин Д.Ф.
Полимеризация стирола и метилметакрилата в присутствии 2,2-диэтил-4,5,5-триметил-2,5-дигидроимидазол-1-оксила
Высокомолекулярные соединения. Серия Б. 2008. Т.50. №12. С.2181-2187. РИНЦ

Опубликована в печати:	1 дек. 2008 г.
Опубликована online:	23 дек. 2008 г.

Web of science	WOS:000261959100013
Scopus	2-s2.0-59849083282
РИНЦ	13572791
OpenAlex	W2022833347