Reductive activation of arenecarbonitriles for the reactions with some carbon-centered electrophiles: the reaction mechanisms and synthetic applications Full article
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Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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| Output data | Year: 2008, Volume: 57, Number: 4, Pages: 768-779 Pages count : DOI: 10.1007/s11172-008-0116-6 | ||||
| Tags | arenecarbonitriles; radical anions; dianions; cyanocyclohexadienyl anions; reductive alkylation and arylation; nucleophilic substitution; electron transfer | ||||
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Abstract:
Synthetic and mechanistic aspects of the developed approach to the activation of aromatic nitriles are considered. The approach is based on the transformation of aromatic nitriles into stable anionic reduced forms. The latter, as shown for the reactions with alkyl halides and cyanoarenes, are promising reactants for the reactions with carbon-centered electrophiles.
Cite:
Vaganova T.A.
, Panteleeva E.V.
, Shteingarts V.D.
Reductive activation of arenecarbonitriles for the reactions with some carbon-centered electrophiles: the reaction mechanisms and synthetic applications
Russian Chemical Bulletin. 2008. V.57. N4. P.768-779. DOI: 10.1007/s11172-008-0116-6 WOS Scopus РИНЦ
Reductive activation of arenecarbonitriles for the reactions with some carbon-centered electrophiles: the reaction mechanisms and synthetic applications
Russian Chemical Bulletin. 2008. V.57. N4. P.768-779. DOI: 10.1007/s11172-008-0116-6 WOS Scopus РИНЦ
ArticleLinkType.TRANSLATED_TO_ORIGINAL:
Ваганова Т.А.
, Пантелеева Е.В.
, Штейнгарц В.Д.
Восстановительная активация аренкарбонитрилов для взаимодействия с некоторыми углерод-центрированными электрофилами: механизм реакций и синтетические приложения
Известия Академии наук. Серия химическая.(RUSS CHEM B+). 2008. №4. С.754-765. РИНЦ
Восстановительная активация аренкарбонитрилов для взаимодействия с некоторыми углерод-центрированными электрофилами: механизм реакций и синтетические приложения
Известия Академии наук. Серия химическая.(RUSS CHEM B+). 2008. №4. С.754-765. РИНЦ
Dates:
| Published print: | Apr 1, 2008 |
| Published online: | Apr 15, 2009 |
Identifiers:
| Web of science | WOS:000264400900006 |
| Scopus | 2-s2.0-64949123328 |
| Elibrary | 13582183 |
| OpenAlex | W1983910337 |