Catalytic activity of systems based on titanium bis(phenoxy imine) complexes: Effect of the ligand structure

Catalytic activity of systems based on titanium bis(phenoxy imine) complexes: Effect of the ligand structure Full article

Journal

Russian Journal of Applied Chemistry
ISSN: 1070-4272 , E-ISSN: 1608-3296

Output data

Year: 2007, Volume: 80, Number: 9, Pages: 1515-1522 Pages count : DOI: 10.1134/S1070427207090145

Authors

Malinskaya M. Yu. , Ivancheva N. I. , Oleinik I. I. , Tolstikov G. A. , Ivanchev S. S.

Affiliations

1	(Данные Web of science) Russian Acad Sci, Boreskov Inst Catl, St Petersburg Branch, Siberian Div, St Petersburg, Russia
2	(Данные Web of science) Russian Acad Sci, Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Div, Novosibirsk, Russia

Polymerization of ethylene at 30-70 degrees C in the presence of catalytic systems based on titanium bis(phenoxy imine) complexes of various structures, activated with methylalumoxane, was studied. An attempt was made to systematize the effect of substituents in ligands, to find correlations, to account for the results obtained, and to reveal conditions under which the reaction occurs by the "living" polymerization mechanism. Some properties and structural features of the polyethylenes obtained were determined.

Malinskaya M.Y. , Ivancheva N.I. , Oleinik I.I. , Tolstikov G.A. , Ivanchev S.S.
Catalytic activity of systems based on titanium bis(phenoxy imine) complexes: Effect of the ligand structure
Russian Journal of Applied Chemistry. 2007. V.80. N9. P.1515-1522. DOI: 10.1134/S1070427207090145 WOS Scopus РИНЦ

Published print:

Sep 1, 2007

Web of science	WOS:000250622800014
Scopus	2-s2.0-35448957742
Elibrary	13540394
OpenAlex	W2000568502