Catalytic activity of systems based on titanium bis(phenoxy imine) complexes: Effect of the ligand structure

Catalytic activity of systems based on titanium bis(phenoxy imine) complexes: Effect of the ligand structure Научная публикация

Журнал

Russian Journal of Applied Chemistry
ISSN: 1070-4272 , E-ISSN: 1608-3296

Вых. Данные

Год: 2007, Том: 80, Номер: 9, Страницы: 1515-1522 Страниц : DOI: 10.1134/S1070427207090145

Авторы

Malinskaya M. Yu. , Ivancheva N. I. , Oleinik I. I. , Tolstikov G. A. , Ivanchev S. S.

Организации

1	(Данные Web of science) Russian Acad Sci, Boreskov Inst Catl, St Petersburg Branch, Siberian Div, St Petersburg, Russia
2	(Данные Web of science) Russian Acad Sci, Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Div, Novosibirsk, Russia

Polymerization of ethylene at 30-70 degrees C in the presence of catalytic systems based on titanium bis(phenoxy imine) complexes of various structures, activated with methylalumoxane, was studied. An attempt was made to systematize the effect of substituents in ligands, to find correlations, to account for the results obtained, and to reveal conditions under which the reaction occurs by the "living" polymerization mechanism. Some properties and structural features of the polyethylenes obtained were determined.

Malinskaya M.Y. , Ivancheva N.I. , Oleinik I.I. , Tolstikov G.A. , Ivanchev S.S.
Catalytic activity of systems based on titanium bis(phenoxy imine) complexes: Effect of the ligand structure
Russian Journal of Applied Chemistry. 2007. V.80. N9. P.1515-1522. DOI: 10.1134/S1070427207090145 WOS Scopus РИНЦ

Опубликована в печати:

1 сент. 2007 г.

Web of science	WOS:000250622800014
Scopus	2-s2.0-35448957742
РИНЦ	13540394
OpenAlex	W2000568502