Electrochemical reduction of decafluorobenzil in DMF on a platinum electrode

Electrochemical reduction of decafluorobenzil in DMF on a platinum electrode Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2007, Volume: 43, Number: 8, Pages: 1158-1162 Pages count : 5 DOI: 10.1134/S1070428007080118

Authors

Vasil'eva N.V. , Irtegova I.G.

Affiliations

1	(Данные Web of science) Russian Acad Sci, Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Div, Novosibirsk 630090, Russia

The mechanism of electrochemical reduction of decafluorobenzil on a platinum electrode in DMF was investigated by cyclic voltammetry. The first reduction peak corresponded to a reversible single-electron transfer leading to the formation of a relatively stable anion-radical whose ESR spectrum was registered and characterized. The second peak corresponded to the reduction of the anion-radical into an unstable dianion that quickly reacted with initial decafluorobenzil, and the arising species (or its transformation product) at the given potential underwent further reduction. The effect of fluorine on the potentials and on the mechanism of the electrochemical reduction of decafluorobenzil was considered.

Vasil'eva N.V. , Irtegova I.G.
Electrochemical reduction of decafluorobenzil in DMF on a platinum electrode
Russian Journal of Organic Chemistry. 2007. V.43. N8. P.1158-1162. DOI: 10.1134/S1070428007080118 WOS Scopus РИНЦ

Васильева Н.В. , Иртегова И.Г.
Электрохимическое восстановление декафторбензила в дмфа на платиновом электроде
Журнал органической химии (RUSS J ORG CHEM+). 2007. Т.43. №8. С.1165-1169. РИНЦ

Published print:

Aug 1, 2007

Web of science	WOS:000249631300011
Scopus	2-s2.0-34648829013
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