Реферат: The mechanism of electrochemical reduction of decafluorobenzil on a platinum electrode in DMF was investigated by cyclic voltammetry. The first reduction peak corresponded to a reversible single-electron transfer leading to the formation of a relatively stable anion-radical whose ESR spectrum was registered and characterized. The second peak corresponded to the reduction of the anion-radical into an unstable dianion that quickly reacted with initial decafluorobenzil, and the arising species (or its transformation product) at the given potential underwent further reduction. The effect of fluorine on the potentials and on the mechanism of the electrochemical reduction of decafluorobenzil was considered.

Библиографическая ссылка: Vasil'eva N.V. , Irtegova I.G.
Electrochemical reduction of decafluorobenzil in DMF on a platinum electrode
Russian Journal of Organic Chemistry. 2007. V.43. N8. P.1158-1162. DOI: 10.1134/S1070428007080118 WOS Scopus РИНЦ

Оригинальная версия: Васильева Н.В. , Иртегова И.Г.
Электрохимическое восстановление декафторбензила в дмфа на платиновом электроде
Журнал органической химии (RUSS J ORG CHEM+). 2007. Т.43. №8. С.1165-1169. РИНЦ

Даты:

Опубликована в печати:

1 авг. 2007 г.

Идентификаторы:

Web of science	WOS:000249631300011
Scopus	2-s2.0-34648829013
РИНЦ	13555262
OpenAlex	W2088270409

Альметрики: