Distinct reactivities of cis- and trans-RFCF=CFBF2 towards XeF2 and the first synthesis of a [trans-RFCF=CFXe](+) salt

Distinct reactivities of cis- and trans-RFCF=CFBF2 towards XeF2 and the first synthesis of a [trans-RFCF=CFXe](+) salt Full article

Journal

Mendeleev Communications
ISSN: 0959-9436

Output data

Year: 2007, Volume: 17, Number: 3, Pages: 137-138 Pages count : 2 DOI: 10.1016/j.mencom.2007.05.001

Authors

Frohn Hermann-Josef ¹ , Bardin Vadim V. ²

Affiliations

1	(Данные Web of science) Univ Duisburg Essen, Dept Chem, D-47048 Duisburg, Germany
2	(Данные Web of science) Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

The competitive reaction of C4F9CF=CFBF2 (Cis: trans = 1.2: 1) with XeF2 demonstrated for the first time a remarkably lower reaction rate of the trans isomer with respect to the cis isomer in the xenodeborylation reaction (formation of the [C4F9CF=CFXe](+) cation with a cis: trans ratio of 2.5 to 4:1) and allowed us to develop reaction conditions for the syntheses of [trans-C4F9CF=CFXe](+) salts.

Frohn H-J. , Bardin V.V.
Distinct reactivities of cis- and trans-RFCF=CFBF2 towards XeF2 and the first synthesis of a [trans-RFCF=CFXe](+) salt
Mendeleev Communications. 2007. V.17. N3. P.137-138. DOI: 10.1016/j.mencom.2007.05.001 WOS Scopus РИНЦ

Published print:

May 1, 2007

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