Distinct reactivities of cis- and trans-RFCF=CFBF2 towards XeF2 and the first synthesis of a [trans-RFCF=CFXe](+) salt

Distinct reactivities of cis- and trans-RFCF=CFBF2 towards XeF2 and the first synthesis of a [trans-RFCF=CFXe](+) salt Научная публикация

Журнал

Mendeleev Communications
ISSN: 0959-9436

Вых. Данные

Год: 2007, Том: 17, Номер: 3, Страницы: 137-138 Страниц : 2 DOI: 10.1016/j.mencom.2007.05.001

Авторы

Frohn Hermann-Josef ¹ , Bardin Vadim V. ²

Организации

1	(Данные Web of science) Univ Duisburg Essen, Dept Chem, D-47048 Duisburg, Germany
2	(Данные Web of science) Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

The competitive reaction of C4F9CF=CFBF2 (Cis: trans = 1.2: 1) with XeF2 demonstrated for the first time a remarkably lower reaction rate of the trans isomer with respect to the cis isomer in the xenodeborylation reaction (formation of the [C4F9CF=CFXe](+) cation with a cis: trans ratio of 2.5 to 4:1) and allowed us to develop reaction conditions for the syntheses of [trans-C4F9CF=CFXe](+) salts.

Frohn H-J. , Bardin V.V.
Distinct reactivities of cis- and trans-RFCF=CFBF2 towards XeF2 and the first synthesis of a [trans-RFCF=CFXe](+) salt
Mendeleev Communications. 2007. V.17. N3. P.137-138. DOI: 10.1016/j.mencom.2007.05.001 WOS Scopus РИНЦ

Опубликована в печати:

1 мая 2007 г.

Web of science	WOS:000247663300001
Scopus	2-s2.0-34249035508
РИНЦ	13562102
OpenAlex	W2012924114