Synthesis of alpha-amino oximes and bis-alpha-amino oximes from the monoterpene hydrocarbons 3-carene and alpha-pinene and alpha,omega-diamines

Synthesis of alpha-amino oximes and bis-alpha-amino oximes from the monoterpene hydrocarbons 3-carene and alpha-pinene and alpha,omega-diamines Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 2001, Volume: 50, Number: 11, Pages: 2106-2112 Pages count : DOI: 10.1023/A:1015097200993

Tags

monoterpenoids; 3-carene; alpha-pinene; nitroso chlorides; alpha-amino oximes; bis-alpha-amino oximes; 1,2-diaminoethane; 1,3-diaminopropane; piperazine; 1,6-diaminohexane; diethylenetriamine; H-1 and C-13 NMR

Authors

Petukhov PA , Bizyaev SN , Tkachev AV

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, NN Vorozhtsov Inst Organ Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, Dept Nat Sci, Novosibirsk 630090, Russia

The reaction of nitroso chlorides of natural monoterpene hydrocarbons, 3-carene and alpha-pinene, with simple alpha,omega-diamines (1,2-diaminoethane, 1,3-diaminopropane, piperazine, 1,6-diaminohexane, diethylenetriamine) results in the formation of alpha-amino oximes and bis-alpha-amino oximes. The product structures were proved by spectroscopy. The procedures of separation and purification of diamino oximes and diamino dioximes are described. Detailed analysis of the H-1 and C-13 NMR spectra of the new chiral nitrogen-containing derivatives was carried out.

Petukhov P. , Bizyaev S. , Tkachev A.
Synthesis of alpha-amino oximes and bis-alpha-amino oximes from the monoterpene hydrocarbons 3-carene and alpha-pinene and alpha,omega-diamines
Russian Chemical Bulletin. 2001. V.50. N11. P.2106-2112. DOI: 10.1023/A:1015097200993 WOS Scopus РИНЦ

Web of science	WOS:000175056400024
Scopus	2-s2.0-0035541781
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