Synthesis of alpha-amino oximes and bis-alpha-amino oximes from the monoterpene hydrocarbons 3-carene and alpha-pinene and alpha,omega-diamines

Synthesis of alpha-amino oximes and bis-alpha-amino oximes from the monoterpene hydrocarbons 3-carene and alpha-pinene and alpha,omega-diamines Научная публикация

Журнал

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Вых. Данные

Год: 2001, Том: 50, Номер: 11, Страницы: 2106-2112 Страниц : DOI: 10.1023/A:1015097200993

Ключевые слова

monoterpenoids; 3-carene; alpha-pinene; nitroso chlorides; alpha-amino oximes; bis-alpha-amino oximes; 1,2-diaminoethane; 1,3-diaminopropane; piperazine; 1,6-diaminohexane; diethylenetriamine; H-1 and C-13 NMR

Авторы

Petukhov PA , Bizyaev SN , Tkachev AV

Организации

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, NN Vorozhtsov Inst Organ Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, Dept Nat Sci, Novosibirsk 630090, Russia

The reaction of nitroso chlorides of natural monoterpene hydrocarbons, 3-carene and alpha-pinene, with simple alpha,omega-diamines (1,2-diaminoethane, 1,3-diaminopropane, piperazine, 1,6-diaminohexane, diethylenetriamine) results in the formation of alpha-amino oximes and bis-alpha-amino oximes. The product structures were proved by spectroscopy. The procedures of separation and purification of diamino oximes and diamino dioximes are described. Detailed analysis of the H-1 and C-13 NMR spectra of the new chiral nitrogen-containing derivatives was carried out.

Petukhov P. , Bizyaev S. , Tkachev A.
Synthesis of alpha-amino oximes and bis-alpha-amino oximes from the monoterpene hydrocarbons 3-carene and alpha-pinene and alpha,omega-diamines
Russian Chemical Bulletin. 2001. V.50. N11. P.2106-2112. DOI: 10.1023/A:1015097200993 WOS Scopus РИНЦ

Web of science	WOS:000175056400024
Scopus	2-s2.0-0035541781
РИНЦ	13374426
OpenAlex	W2950488595