(Fluoroorgano)fluoroboranes and -fluoroborates. Part 3. Polyfluoroalken-1-yldifluoroboranes

(Fluoroorgano)fluoroboranes and -fluoroborates. Part 3. Polyfluoroalken-1-yldifluoroboranes Full article

Journal

Journal of Organometallic Chemistry
ISSN: 0022-328X

Output data

Year: 2001, Volume: 631, Number: 1-2, Pages: 54-58 Pages count : DOI: 10.1016/S0022-328X(01)00858-0

Tags

boranes; borates; polyfluoroalken-1-yl boron compounds; NMR

Authors

Frohn HJ , Bardin VV

Affiliations

1	(Данные Web of science) Univ Duisburg Gesamthsch, Fachgebiet Anorgan Chem, D-47048 Duisburg, Germany
2	(Данные Web of science) NN Vorozhtsov Inst Organ Chem, Novosibirsk 630090, Russia

Polyfluoroalken-1-yldifluoroboranes RCF=CFBF2 (R = F, cis-, trans-Cl, trans-C4F9, cis-C2F5, cis-C6F13, trans-C4H9, trans-C6H5) were prepared by defluoridation of the corresponding fluoroborate salts K[RCF=CFBF3] using boron trifluoride in dichloromethane or fluorotrichloromethane. The alkenylboranes were characterised by H-1-, B-11- and F-19-NMR spectroscopy. Their reactivity towards ether, water and anhydrous HF was investigated. (C) 2001 Elsevier Science V.B. All rights reserved.

Frohn H. , Bardin V.
(Fluoroorgano)fluoroboranes and -fluoroborates. Part 3. Polyfluoroalken-1-yldifluoroboranes
Journal of Organometallic Chemistry. 2001. V.631. N1-2. P.54-58. DOI: 10.1016/S0022-328X(01)00858-0 WOS Scopus РИНЦ

Published print:

Aug 1, 2001

Web of science	WOS:000170950900009
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