(Fluoroorgano)fluoroboranes and -fluoroborates. Part 3. Polyfluoroalken-1-yldifluoroboranes

(Fluoroorgano)fluoroboranes and -fluoroborates. Part 3. Polyfluoroalken-1-yldifluoroboranes Научная публикация

Журнал

Journal of Organometallic Chemistry
ISSN: 0022-328X

Вых. Данные

Год: 2001, Том: 631, Номер: 1-2, Страницы: 54-58 Страниц : DOI: 10.1016/S0022-328X(01)00858-0

Ключевые слова

boranes; borates; polyfluoroalken-1-yl boron compounds; NMR

Авторы

Frohn HJ , Bardin VV

Организации

1	(Данные Web of science) Univ Duisburg Gesamthsch, Fachgebiet Anorgan Chem, D-47048 Duisburg, Germany
2	(Данные Web of science) NN Vorozhtsov Inst Organ Chem, Novosibirsk 630090, Russia

Polyfluoroalken-1-yldifluoroboranes RCF=CFBF2 (R = F, cis-, trans-Cl, trans-C4F9, cis-C2F5, cis-C6F13, trans-C4H9, trans-C6H5) were prepared by defluoridation of the corresponding fluoroborate salts K[RCF=CFBF3] using boron trifluoride in dichloromethane or fluorotrichloromethane. The alkenylboranes were characterised by H-1-, B-11- and F-19-NMR spectroscopy. Their reactivity towards ether, water and anhydrous HF was investigated. (C) 2001 Elsevier Science V.B. All rights reserved.

Frohn H. , Bardin V.
(Fluoroorgano)fluoroboranes and -fluoroborates. Part 3. Polyfluoroalken-1-yldifluoroboranes
Journal of Organometallic Chemistry. 2001. V.631. N1-2. P.54-58. DOI: 10.1016/S0022-328X(01)00858-0 WOS Scopus РИНЦ

Опубликована в печати:

1 авг. 2001 г.

Web of science	WOS:000170950900009
Scopus	2-s2.0-0002498677
РИНЦ	13377037
OpenAlex	W2057431136