A preparative method for perfluoroalkyltrifluoroborates and perfluoroalkyldifluoroboranes

A preparative method for perfluoroalkyltrifluoroborates and perfluoroalkyldifluoroboranes Full article

Journal

Zeitschrift fur Anorganische und Allgemeine Chemie
ISSN: 0044-2313

Output data

Year: 2001, Volume: 627, Number: 1, Pages: 15-16 Pages count : DOI: 10.1002/1521-3749(200101)627:1<15::AID-ZAAC15>3.0.CO;2-A

Tags

borate; borane; perfluoroalkyl

Authors

Frohn HJ , Bardin VV

Affiliations

1	(Данные Web of science) Univ Duisburg Gesamthsch, Fachgebiet Anorgan Chem, D-47048 Duisburg, Germany
2	(Данные Web of science) NN Vorozhtsov Inst Organ Chem, Novosibirsk, Russia

A convenient new preparative method for the unknown class of perfluoroalkyltrifluoroborates K[CnF2n + 1BF3] and perfluoroalkyldifluoroboranes CnF2n + 1BF2 (n > 1) is elaborated. The perfluoroalkyl group is introduced into the boric acid ester by using CnF2n + 1MgBr. Treatment with K[HF2] and HF,, results in K[CnF2n + 1BF3] which can be defluoridated by AsF5 to the corresponding boranes CnF2n + 1BF2.

Frohn H. , Bardin V.
A preparative method for perfluoroalkyltrifluoroborates and perfluoroalkyldifluoroboranes
Zeitschrift fur Anorganische und Allgemeine Chemie. 2001. V.627. N1. P.15-16. DOI: 10.1002/1521-3749(200101)627:1<15::AID-ZAAC15>3.0.CO;2-A WOS Scopus РИНЦ

Published print:

Jan 1, 2001

Web of science	WOS:000166588300007
Scopus	2-s2.0-0035583385
Elibrary	13383736
OpenAlex	W2008229208