A preparative method for perfluoroalkyltrifluoroborates and perfluoroalkyldifluoroboranes Научная публикация
| Журнал |
Zeitschrift fur Anorganische und Allgemeine Chemie
ISSN: 0044-2313 |
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| Вых. Данные | Год: 2001, Том: 627, Номер: 1, Страницы: 15-16 Страниц : DOI: 10.1002/1521-3749(200101)627:1<15::AID-ZAAC15>3.0.CO;2-A | ||||
| Ключевые слова | borate; borane; perfluoroalkyl | ||||
| Авторы |
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| Организации |
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Реферат:
A convenient new preparative method for the unknown class of perfluoroalkyltrifluoroborates K[CnF2n + 1BF3] and perfluoroalkyldifluoroboranes CnF2n + 1BF2 (n > 1) is elaborated. The perfluoroalkyl group is introduced into the boric acid ester by using CnF2n + 1MgBr. Treatment with K[HF2] and HF,, results in K[CnF2n + 1BF3] which can be defluoridated by AsF5 to the corresponding boranes CnF2n + 1BF2.
Библиографическая ссылка:
Frohn H.
, Bardin V.
A preparative method for perfluoroalkyltrifluoroborates and perfluoroalkyldifluoroboranes
Zeitschrift fur Anorganische und Allgemeine Chemie. 2001. V.627. N1. P.15-16. DOI: 10.1002/1521-3749(200101)627:1<15::AID-ZAAC15>3.0.CO;2-A WOS Scopus РИНЦ
A preparative method for perfluoroalkyltrifluoroborates and perfluoroalkyldifluoroboranes
Zeitschrift fur Anorganische und Allgemeine Chemie. 2001. V.627. N1. P.15-16. DOI: 10.1002/1521-3749(200101)627:1<15::AID-ZAAC15>3.0.CO;2-A WOS Scopus РИНЦ
Даты:
| Опубликована в печати: | 1 янв. 2001 г. |
Идентификаторы:
| Web of science | WOS:000166588300007 |
| Scopus | 2-s2.0-0035583385 |
| РИНЦ | 13383736 |
| OpenAlex | W2008229208 |