A convenient preparation of pentafluorophenyl(fluoro) silanes: Reactivity of pentafluorophenyltrifluorosilane

A convenient preparation of pentafluorophenyl(fluoro) silanes: Reactivity of pentafluorophenyltrifluorosilane Full article

Journal

Journal of Organometallic Chemistry
ISSN: 0022-328X

Output data

Year: 1996, Volume: 506, Number: 1-2, Pages: 155-164 Pages count : 10 DOI: 10.1016/0022-328X(95)05676-G

Tags

pentafluorophenylhalogenosilanes; C-Si bond cleavage; nucleophilic arylation of electrophiles

Authors

Frohn H.J. ¹ , Giesen M. ¹ , Klose A. ¹ , Lewin A. ¹ , Bardin V.V. ²

Affiliations

1	Fachgebiet Anorganische Chemie, Gerhard-Mercator-Universität Duisburg, Lotharstr. 1, D-47048 Duisburg, Germany
2	Institute of Organic Chemistry, 630090 Novosibirsk, Russia

Pentafluorophenyl(fluoro)silanes (C6F5)(n)SiF4-n (n = 1, 2) were prepared from the corresponding ethoxysilanes by sequential chlorodeethoxylation with SOCl2 and fluoridation of chlorosilanes with SbF3. The conversion of C6F5Si(OEt)(3) and C6F5SiCl3 into C6F5SiF3 with anhydrous HF was described. Some reactions of C6F5SiF3 with electrophiles and nucleophiles were studied.

Frohn H.J. , Giesen M. , Klose A. , Lewin A. , Bardin V.V.
A convenient preparation of pentafluorophenyl(fluoro) silanes: Reactivity of pentafluorophenyltrifluorosilane
Journal of Organometallic Chemistry. 1996. V.506. N1-2. P.155-164. DOI: 10.1016/0022-328X(95)05676-G WOS Scopus РИНЦ

Published print:

Jan 1, 1996

Web of science	WOS:A1996TP33800021
Scopus	2-s2.0-0030525285
Elibrary	13224803
OpenAlex	W2013233902