A convenient preparation of pentafluorophenyl(fluoro) silanes: Reactivity of pentafluorophenyltrifluorosilane Научная публикация
| Журнал |
Journal of Organometallic Chemistry
ISSN: 0022-328X |
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| Вых. Данные | Год: 1996, Том: 506, Номер: 1-2, Страницы: 155-164 Страниц : 10 DOI: 10.1016/0022-328X(95)05676-G | ||||
| Ключевые слова | pentafluorophenylhalogenosilanes; C-Si bond cleavage; nucleophilic arylation of electrophiles | ||||
| Авторы |
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| Организации |
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Реферат:
Pentafluorophenyl(fluoro)silanes (C6F5)(n)SiF4-n (n = 1, 2) were prepared from the corresponding ethoxysilanes by sequential chlorodeethoxylation with SOCl2 and fluoridation of chlorosilanes with SbF3. The conversion of C6F5Si(OEt)(3) and C6F5SiCl3 into C6F5SiF3 with anhydrous HF was described. Some reactions of C6F5SiF3 with electrophiles and nucleophiles were studied.
Библиографическая ссылка:
Frohn H.J.
, Giesen M.
, Klose A.
, Lewin A.
, Bardin V.V.
A convenient preparation of pentafluorophenyl(fluoro) silanes: Reactivity of pentafluorophenyltrifluorosilane
Journal of Organometallic Chemistry. 1996. V.506. N1-2. P.155-164. DOI: 10.1016/0022-328X(95)05676-G WOS Scopus РИНЦ
A convenient preparation of pentafluorophenyl(fluoro) silanes: Reactivity of pentafluorophenyltrifluorosilane
Journal of Organometallic Chemistry. 1996. V.506. N1-2. P.155-164. DOI: 10.1016/0022-328X(95)05676-G WOS Scopus РИНЦ
Даты:
| Опубликована в печати: | 1 янв. 1996 г. |
Идентификаторы:
| Web of science | WOS:A1996TP33800021 |
| Scopus | 2-s2.0-0030525285 |
| РИНЦ | 13224803 |
| OpenAlex | W2013233902 |