SYNTHESIS OF ALIPHATIC 1,2-BISHYDROXYLAMINES FROM 1,3-DIHYDROXYIMIDAZOLIDINES - THE CRYSTAL-STRUCTURE OF 1,2-BISHYDROXYLAMINOCYCLOALKANES

SYNTHESIS OF ALIPHATIC 1,2-BISHYDROXYLAMINES FROM 1,3-DIHYDROXYIMIDAZOLIDINES - THE CRYSTAL-STRUCTURE OF 1,2-BISHYDROXYLAMINOCYCLOALKANES Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 1993, Volume: 42, Number: 5, Pages: 851-857 Pages count : 7 DOI: 10.1007/BF00698944

Tags

1-HYDROXY-3-IMIDAZOLINE-3-OXIDES; 1,3-DIHYDROXYIMIDAZOLIDINES; 1,2-BISHYDROXYLAMINES; NITRONES, REDUCTION; 1,2-BIS(HYDROXYLAMINO)CYCLOALKANES, CRYSTAL STRUCTURE

Authors

Mazhukin D.G. ¹ , Tikhonov A.Ya. ¹ , Volodarskii L.B. ¹ , Konovalova E.P. ¹ , Tikhonova L.A. ¹ , Bagryanskaya I.Yu. ¹ , Gatilov Yu .V. ¹

Affiliations

1	Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation

Reduction of 1-hydroxy-3-imidazoline-3-oxides with NaBH4 gives 1,3-dihydroxyimidazolidines. The latter on subsequent treatment with NH2OH.HCl in EtOH or in hydrochloric acid afford 1,2-bishydroxylamines. An X-ray study of 1,2-bishydroxylaminocycloalkanes has shown them to be cis-configurated.

Mazhukin D.G. , Tikhonov A.Y. , Volodarskii L.B. , Konovalova E.P. , Tikhonova L.A. , Bagryanskaya I.Y. , Gatilov Y.V.
SYNTHESIS OF ALIPHATIC 1,2-BISHYDROXYLAMINES FROM 1,3-DIHYDROXYIMIDAZOLIDINES - THE CRYSTAL-STRUCTURE OF 1,2-BISHYDROXYLAMINOCYCLOALKANES
Russian Chemical Bulletin. 1993. V.42. N5. P.851-857. DOI: 10.1007/BF00698944 WOS Scopus РИНЦ

Published print:

May 1, 1993

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