SYNTHESIS OF ALIPHATIC 1,2-BISHYDROXYLAMINES FROM 1,3-DIHYDROXYIMIDAZOLIDINES - THE CRYSTAL-STRUCTURE OF 1,2-BISHYDROXYLAMINOCYCLOALKANES

SYNTHESIS OF ALIPHATIC 1,2-BISHYDROXYLAMINES FROM 1,3-DIHYDROXYIMIDAZOLIDINES - THE CRYSTAL-STRUCTURE OF 1,2-BISHYDROXYLAMINOCYCLOALKANES Научная публикация

Журнал

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Вых. Данные

Год: 1993, Том: 42, Номер: 5, Страницы: 851-857 Страниц : 7 DOI: 10.1007/BF00698944

Ключевые слова

1-HYDROXY-3-IMIDAZOLINE-3-OXIDES; 1,3-DIHYDROXYIMIDAZOLIDINES; 1,2-BISHYDROXYLAMINES; NITRONES, REDUCTION; 1,2-BIS(HYDROXYLAMINO)CYCLOALKANES, CRYSTAL STRUCTURE

Авторы

Mazhukin D.G. ¹ , Tikhonov A.Ya. ¹ , Volodarskii L.B. ¹ , Konovalova E.P. ¹ , Tikhonova L.A. ¹ , Bagryanskaya I.Yu. ¹ , Gatilov Yu .V. ¹

Организации

1	Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation

Reduction of 1-hydroxy-3-imidazoline-3-oxides with NaBH4 gives 1,3-dihydroxyimidazolidines. The latter on subsequent treatment with NH2OH.HCl in EtOH or in hydrochloric acid afford 1,2-bishydroxylamines. An X-ray study of 1,2-bishydroxylaminocycloalkanes has shown them to be cis-configurated.

Mazhukin D.G. , Tikhonov A.Y. , Volodarskii L.B. , Konovalova E.P. , Tikhonova L.A. , Bagryanskaya I.Y. , Gatilov Y.V.
SYNTHESIS OF ALIPHATIC 1,2-BISHYDROXYLAMINES FROM 1,3-DIHYDROXYIMIDAZOLIDINES - THE CRYSTAL-STRUCTURE OF 1,2-BISHYDROXYLAMINOCYCLOALKANES
Russian Chemical Bulletin. 1993. V.42. N5. P.851-857. DOI: 10.1007/BF00698944 WOS Scopus РИНЦ

Опубликована в печати:

1 мая 1993 г.

Web of science	WOS:A1993NJ89900016
Scopus	2-s2.0-33748398166
РИНЦ	30891470
OpenAlex	W2317854765