FLUOROINDENES .13. TRANSFORMATIONS OF POLYFLUORINATED INDENES AND 1-ALKYLIDENEINDANS IN THE H2O2-HF-SBF5 SYSTEM

FLUOROINDENES .13. TRANSFORMATIONS OF POLYFLUORINATED INDENES AND 1-ALKYLIDENEINDANS IN THE H2O2-HF-SBF5 SYSTEM Full article

Journal

BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE
ISSN: 1063-5211

Output data

Year: 1992, Volume: 41, Number: 6, Pages: 1104-1110 Pages count : 7 DOI: 10.1007/BF00866597

Tags

POLYFLUORINATED INDENES; ALKYLIDENEINDANS; ELECTROPHILIC HYDROXYFLUORINATION; POLYFLUORINATED KETONES; BAEYER-VILLIGER REACTION

Authors

Chuikov I.P. ¹ , Karpov V.M. ¹ , Platonov V.E. ¹

Affiliations

1	N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry of Siberian Branch of Russian Academy of Sciences

The reaction of perfluorinated indene, 3-methylindene, and 1-methylene- and 1-ethylideneindans with hydrogen peroxide in the hydrogen fluoride-antimony pentafluoride medium takes place at the multiple bond of the substrate and leads to the oxo derivatives of indan. The process probably takes place through the electrophilic addition of HO+. The C=C bond in perfluoro-3-methylindenone is not affected. In this compound and also in perfluoro-2-indanone and perfluoro-1-methyl-2-indanone the carbonyl group is involved in reaction with hydrogen peroxide in the HF-SbF5 system, and six-membered oxygen-containing heterocyclic compounds are formed.

Chuikov I.P. , Karpov V.M. , Platonov V.E.
FLUOROINDENES .13. TRANSFORMATIONS OF POLYFLUORINATED INDENES AND 1-ALKYLIDENEINDANS IN THE H2O2-HF-SBF5 SYSTEM
BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE. 1992. V.41. N6. P.1104-1110. DOI: 10.1007/BF00866597 WOS Scopus РИНЦ

Published print:

Jun 1, 1992

Web of science	WOS:A1992KU70200012
Scopus	2-s2.0-33750933071
Elibrary	31430642
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