FLUOROINDENES .13. TRANSFORMATIONS OF POLYFLUORINATED INDENES AND 1-ALKYLIDENEINDANS IN THE H2O2-HF-SBF5 SYSTEM Научная публикация
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BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE
ISSN: 1063-5211 |
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| Вых. Данные | Год: 1992, Том: 41, Номер: 6, Страницы: 1104-1110 Страниц : 7 DOI: 10.1007/BF00866597 | ||
| Ключевые слова | POLYFLUORINATED INDENES; ALKYLIDENEINDANS; ELECTROPHILIC HYDROXYFLUORINATION; POLYFLUORINATED KETONES; BAEYER-VILLIGER REACTION | ||
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Реферат:
The reaction of perfluorinated indene, 3-methylindene, and 1-methylene- and 1-ethylideneindans with hydrogen peroxide in the hydrogen fluoride-antimony pentafluoride medium takes place at the multiple bond of the substrate and leads to the oxo derivatives of indan. The process probably takes place through the electrophilic addition of HO+. The C=C bond in perfluoro-3-methylindenone is not affected. In this compound and also in perfluoro-2-indanone and perfluoro-1-methyl-2-indanone the carbonyl group is involved in reaction with hydrogen peroxide in the HF-SbF5 system, and six-membered oxygen-containing heterocyclic compounds are formed.
Библиографическая ссылка:
Chuikov I.P.
, Karpov V.M.
, Platonov V.E.
FLUOROINDENES .13. TRANSFORMATIONS OF POLYFLUORINATED INDENES AND 1-ALKYLIDENEINDANS IN THE H2O2-HF-SBF5 SYSTEM
BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE. 1992. V.41. N6. P.1104-1110. DOI: 10.1007/BF00866597 WOS Scopus РИНЦ
FLUOROINDENES .13. TRANSFORMATIONS OF POLYFLUORINATED INDENES AND 1-ALKYLIDENEINDANS IN THE H2O2-HF-SBF5 SYSTEM
BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE. 1992. V.41. N6. P.1104-1110. DOI: 10.1007/BF00866597 WOS Scopus РИНЦ
Даты:
| Опубликована в печати: | 1 июн. 1992 г. |
Идентификаторы:
| Web of science | WOS:A1992KU70200012 |
| Scopus | 2-s2.0-33750933071 |
| РИНЦ | 31430642 |
| OpenAlex | W2024264900 |