Abstract: New process direction was found in the reaction of polyfluoroarenethiols with fluorodichloromethane, chloroform, and bromoform in an alkaline medium consisting in the replacement of the thiol group by a hydrogen atom. This process competes with the formation of expected products, dihalomethyl polyfluoro-aryl sulfides and tris(arylsulfanyl)methanes. In reaction of 2,3,5,6-tetrafluorobenzenethiol with dichloro-methane bis(2,3,5,6-tetrafluorophenylsulfanyl)methane was obtained. Reactions of polyfluoroarenethiols with pentafluorobenzyl chloride occur mainly with the substitution of the chlorine atom, with pentafluorobenzal chloride and with pentafluorobenzotrichloride a substitution of a fluorine atom in the para-position takes place.

Cite: Bredikhin R.A. , Maksimov A.M. , Gatilov Y.V. , Kireenkov V.V. , Platonov V.E.
Reactions of polyfluorobenzenethiols with polyhalomethanes and their derivatives in an alkaline medium
Russian Journal of Organic Chemistry. 2015. V.51. N11. P.1551-1559. DOI: 10.1134/S1070428015110068 WOS Scopus РИНЦ

ArticleLinkType.TRANSLATED_TO_ORIGINAL: Бредихин Р.А. , Максимов А.М. , Гатилов Ю.В. , Киреенков В.В. , Платонов В.Е.
Реакции полифторбензолтиолов с полигалогенметанами и их производными в щелочной среде
Журнал органической химии (RUSS J ORG CHEM+). 2015. Т.51. №11. С.1582-1590. РИНЦ

Dates:

Published print:	Nov 1, 2015
Published online:	Dec 24, 2015

Identifiers:

Web of science	WOS:000367346500006
Scopus	2-s2.0-84951287023
Elibrary	26806933
OpenAlex	W2251590209

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