Reactions of polyfluorobenzenethiols with polyhalomethanes and their derivatives in an alkaline medium

Reactions of polyfluorobenzenethiols with polyhalomethanes and their derivatives in an alkaline medium Научная публикация

Журнал

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Вых. Данные

Год: 2015, Том: 51, Номер: 11, Страницы: 1551-1559 Страниц : 9 DOI: 10.1134/S1070428015110068

Авторы

Bredikhin R.A. ^1,2 , Maksimov A.M. ¹ , Gatilov Yu V. ^1,2 , Kireenkov V.V. ³ , Platonov V.E. ¹

Организации

1	Russian Acad Sci, Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia
2	Novosibirsk State Univ, Novosibirsk 630090, Russia
3	Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, St Petersburg 196140, Russia

New process direction was found in the reaction of polyfluoroarenethiols with fluorodichloromethane, chloroform, and bromoform in an alkaline medium consisting in the replacement of the thiol group by a hydrogen atom. This process competes with the formation of expected products, dihalomethyl polyfluoro-aryl sulfides and tris(arylsulfanyl)methanes. In reaction of 2,3,5,6-tetrafluorobenzenethiol with dichloro-methane bis(2,3,5,6-tetrafluorophenylsulfanyl)methane was obtained. Reactions of polyfluoroarenethiols with pentafluorobenzyl chloride occur mainly with the substitution of the chlorine atom, with pentafluorobenzal chloride and with pentafluorobenzotrichloride a substitution of a fluorine atom in the para-position takes place.

Bredikhin R.A. , Maksimov A.M. , Gatilov Y.V. , Kireenkov V.V. , Platonov V.E.
Reactions of polyfluorobenzenethiols with polyhalomethanes and their derivatives in an alkaline medium
Russian Journal of Organic Chemistry. 2015. V.51. N11. P.1551-1559. DOI: 10.1134/S1070428015110068 WOS Scopus РИНЦ

Бредихин Р.А. , Максимов А.М. , Гатилов Ю.В. , Киреенков В.В. , Платонов В.Е.
Реакции полифторбензолтиолов с полигалогенметанами и их производными в щелочной среде
Журнал органической химии (RUSS J ORG CHEM+). 2015. Т.51. №11. С.1582-1590. РИНЦ

Опубликована в печати:	1 нояб. 2015 г.
Опубликована online:	24 дек. 2015 г.

Web of science	WOS:000367346500006
Scopus	2-s2.0-84951287023
РИНЦ	26806933
OpenAlex	W2251590209