Reactions of Polyfluoroaromatic Organozinc Compounds with Oxalyl Chloride in DMF. Synthesis of Polyfluoroaromatic Aldehydes

Reactions of Polyfluoroaromatic Organozinc Compounds with Oxalyl Chloride in DMF. Synthesis of Polyfluoroaromatic Aldehydes Full article

Journal

Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350

Output data

Year: 2020, Volume: 90, Number: 12, Pages: 2264-2272 Pages count : 9 DOI: 10.1134/S1070363220120087

Tags

polyfluoroaromatic organozinc compounds; oxalyl chloride; DMF; Vilsmeier– Haack reagent; polyfluoroaromatic aldehydes

Authors

Vinogradov A.S. ¹ , Platonov V.E. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

The reaction of polyfluoroaromatic organozinc compounds with oxalyl chloride in DMF proceeds involving the Vilsmeier-Haack reagent with the formation of polyfluoroaromatic aldehydes as the major products. The use of CuI makes it possible to increase the yield of the target aldehydes.

Vinogradov A.S. , Platonov V.E.
Reactions of Polyfluoroaromatic Organozinc Compounds with Oxalyl Chloride in DMF. Synthesis of Polyfluoroaromatic Aldehydes
Russian Journal of General Chemistry. 2020. V.90. N12. P.2264-2272. DOI: 10.1134/S1070363220120087 WOS Scopus РИНЦ

Виноградов А.С. , Платонов В.Е.
РЕАКЦИИ ПОЛИФТОРАРОМАТИЧЕСКИХ ЦИНКОРГАНИЧЕСКИХ СОЕДИНЕНИЙ С ОКСАЛИЛХЛОРИДОМ В ДМФА. СИНТЕЗ ПОЛИФТОРАРОМАТИЧЕСКИХ АЛЬДЕГИДОВ
Журнал общей химии (RUSS J GEN CHEM+). 2020. Т.90. №12. С.1858-1866. DOI: 10.31857/S0044460X20120082 РИНЦ

Published print:	Dec 1, 2020
Published online:	Feb 5, 2021

Web of science	WOS:000615262800008
Scopus	2-s2.0-85100545791
Elibrary	46748336
OpenAlex	W3128621386