Reactions of Polyfluoroaromatic Organozinc Compounds with Oxalyl Chloride in DMF. Synthesis of Polyfluoroaromatic Aldehydes

Reactions of Polyfluoroaromatic Organozinc Compounds with Oxalyl Chloride in DMF. Synthesis of Polyfluoroaromatic Aldehydes Научная публикация

Журнал

Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350

Вых. Данные

Год: 2020, Том: 90, Номер: 12, Страницы: 2264-2272 Страниц : 9 DOI: 10.1134/S1070363220120087

Ключевые слова

polyfluoroaromatic organozinc compounds; oxalyl chloride; DMF; Vilsmeier– Haack reagent; polyfluoroaromatic aldehydes

Авторы

Vinogradov A.S. ¹ , Platonov V.E. ¹

Организации

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

The reaction of polyfluoroaromatic organozinc compounds with oxalyl chloride in DMF proceeds involving the Vilsmeier-Haack reagent with the formation of polyfluoroaromatic aldehydes as the major products. The use of CuI makes it possible to increase the yield of the target aldehydes.

Vinogradov A.S. , Platonov V.E.
Reactions of Polyfluoroaromatic Organozinc Compounds with Oxalyl Chloride in DMF. Synthesis of Polyfluoroaromatic Aldehydes
Russian Journal of General Chemistry. 2020. V.90. N12. P.2264-2272. DOI: 10.1134/S1070363220120087 WOS Scopus РИНЦ

Виноградов А.С. , Платонов В.Е.
РЕАКЦИИ ПОЛИФТОРАРОМАТИЧЕСКИХ ЦИНКОРГАНИЧЕСКИХ СОЕДИНЕНИЙ С ОКСАЛИЛХЛОРИДОМ В ДМФА. СИНТЕЗ ПОЛИФТОРАРОМАТИЧЕСКИХ АЛЬДЕГИДОВ
Журнал общей химии (RUSS J GEN CHEM+). 2020. Т.90. №12. С.1858-1866. DOI: 10.31857/S0044460X20120082 РИНЦ

Опубликована в печати:	1 дек. 2020 г.
Опубликована online:	5 февр. 2021 г.

Web of science	WOS:000615262800008
Scopus	2-s2.0-85100545791
РИНЦ	46748336
OpenAlex	W3128621386