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Synthesis and properties of novel random copolymers made from N-acryloyl piperazine-based monomers and fluoroalkylmethacrylates Full article

Journal Polymer Bulletin
ISSN: 0170-0839 , E-ISSN: 1436-2449
Output data Year: 2015, Volume: 72, Number: 11, Pages: 2783-2796 Pages count : DOI: 10.1007/s00289-015-1435-z
Tags N-acryloyl piperazine-based monomer; Adhesive properties; Fluoroacrylic copolymer; Radical copolymerization; Pressure-sensitive paint; Terpolymers
Authors Shundrina Inna K. 1,3 , Bukhtoyarova Aleksandra D. 1 , Russkikh Vladimlen V. 1 , Parkhomenko Dmitry A. 2 , Shelkovnikov Vladimir V. 1
Affiliations
1 (Данные Web of science) Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia
2 (Данные Web of science) Int Tomog Ctr, Novosibirsk 630090, Russia
3 (Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia

Abstract: New piperazine-based polymerizable monomers were synthesized to modify adhesive properties of fluoromethacrylic copolymer. The new monomers showed good ability to radical copolymerization with fluoroalkylmethacrylates. Amorphous glassy terpolymers were prepared with random distribution units in the macromolecules and weight-average molecular weight (M (w)) 110,000-130,000. The ratio of monomer units in the obtained copolymer is close to the ratio of the monomers in the starting mixture. The terpolymers exhibited excellent solubility in tetrahydrofuran (THF), acetone and alpha,alpha,alpha-trifluorotoluene (TFT). The introduction of new monomers to the macromolecules increased the glass-transition temperatures (T (g)) of terpolymers, significantly improved their thermal stability and adhesion to the aluminum substrate.
Cite: Shundrina I.K. , Bukhtoyarova A.D. , Russkikh V.V. , Parkhomenko D.A. , Shelkovnikov V.V.
Synthesis and properties of novel random copolymers made from N-acryloyl piperazine-based monomers and fluoroalkylmethacrylates
Polymer Bulletin. 2015. V.72. N11. P.2783-2796. DOI: 10.1007/s00289-015-1435-z WOS Scopus РИНЦ
Dates:
Published online: Jun 21, 2015
Published print: Nov 1, 2015
Identifiers:
Web of science WOS:000361427900004
Scopus 2-s2.0-84941942577
Elibrary 24949809
OpenAlex W2239674062
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