Synthesis and properties of novel random copolymers made from N-acryloyl piperazine-based monomers and fluoroalkylmethacrylates

Synthesis and properties of novel random copolymers made from N-acryloyl piperazine-based monomers and fluoroalkylmethacrylates Научная публикация

Журнал

Polymer Bulletin
ISSN: 0170-0839 , E-ISSN: 1436-2449

Вых. Данные

Год: 2015, Том: 72, Номер: 11, Страницы: 2783-2796 Страниц : DOI: 10.1007/s00289-015-1435-z

Ключевые слова

N-acryloyl piperazine-based monomer; Adhesive properties; Fluoroacrylic copolymer; Radical copolymerization; Pressure-sensitive paint; Terpolymers

Авторы

Shundrina Inna K. ^1,3 , Bukhtoyarova Aleksandra D. ¹ , Russkikh Vladimlen V. ¹ , Parkhomenko Dmitry A. ² , Shelkovnikov Vladimir V. ¹

Организации

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Int Tomog Ctr, Novosibirsk 630090, Russia
3	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia

New piperazine-based polymerizable monomers were synthesized to modify adhesive properties of fluoromethacrylic copolymer. The new monomers showed good ability to radical copolymerization with fluoroalkylmethacrylates. Amorphous glassy terpolymers were prepared with random distribution units in the macromolecules and weight-average molecular weight (M (w)) 110,000-130,000. The ratio of monomer units in the obtained copolymer is close to the ratio of the monomers in the starting mixture. The terpolymers exhibited excellent solubility in tetrahydrofuran (THF), acetone and alpha,alpha,alpha-trifluorotoluene (TFT). The introduction of new monomers to the macromolecules increased the glass-transition temperatures (T (g)) of terpolymers, significantly improved their thermal stability and adhesion to the aluminum substrate.

Shundrina I.K. , Bukhtoyarova A.D. , Russkikh V.V. , Parkhomenko D.A. , Shelkovnikov V.V.
Synthesis and properties of novel random copolymers made from N-acryloyl piperazine-based monomers and fluoroalkylmethacrylates
Polymer Bulletin. 2015. V.72. N11. P.2783-2796. DOI: 10.1007/s00289-015-1435-z WOS Scopus РИНЦ

Опубликована online:	21 июн. 2015 г.
Опубликована в печати:	1 нояб. 2015 г.

Web of science	WOS:000361427900004
Scopus	2-s2.0-84941942577
РИНЦ	24949809
OpenAlex	W2239674062