Preparation of Diversely Substituted Triarylmethyl Radicals by the Quenching of Tris(2,3,5,6-tetrathiaaryl)methyl Cations with C-, N-, P-, and S-Nucleophiles

Preparation of Diversely Substituted Triarylmethyl Radicals by the Quenching of Tris(2,3,5,6-tetrathiaaryl)methyl Cations with C-, N-, P-, and S-Nucleophiles Full article

Journal

European Journal of Organic Chemistry
ISSN: 1434-193X , E-ISSN: 1099-0690

Output data

Year: 2014, Volume: 2014, Number: 2, Pages: 371-380 Pages count : DOI: 10.1002/ejoc.201301161

Tags

Carbocations; Radicals; Electron transfer; Nucleophilic addition; Reaction mechanisms

Authors

Tormyshev Victor M. ^1,2 , Rogozhnikova Olga Yu. ¹ , Bowman Michael K. ³ , Trukhin Dmitry V. ¹ , Troitskaya Tatiana I. ¹ , Vasiliev Vladimir G. ¹ , Shundrin Leonid A. ¹ , Halpern Howard J. ⁴

Affiliations

1	(Данные Web of science) Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, Natl Res Univ, Dept Nat Sci, Novosibirsk 630090, Russia
3	(Данные Web of science) Univ Alabama, Dept Chem, Tuscaloosa, AL 35487 USA
4	(Данные Web of science) Univ Chicago, Dept Radiat & Cellular Oncol, Ctr EPR Imaging Vivo Physiol, Chicago, IL 60637 USA

C-, N-, P-, and S-nucleophiles reacted with symmetrical tris(2,3,5,6-tetrathiaaryl)methyl cations, generated from the corresponding triarylmethanols by strong acids, to give a variety of asymmetrical monosubstituted persistent triarylmethyl (TAM) radicals as the major products. The only by-products were symmetrical TAMs.

Tormyshev V.M. , Rogozhnikova O.Y. , Bowman M.K. , Trukhin D.V. , Troitskaya T.I. , Vasiliev V.G. , Shundrin L.A. , Halpern H.J.
Preparation of Diversely Substituted Triarylmethyl Radicals by the Quenching of Tris(2,3,5,6-tetrathiaaryl)methyl Cations with C-, N-, P-, and S-Nucleophiles

European Journal of Organic Chemistry. 2014. V.2014. N2. P.371-380. DOI: 10.1002/ejoc.201301161 WOS Scopus РИНЦ OpenAlex

Full text from publisher

Published online:	Nov 6, 2013
Published print:	Jan 1, 2014

Web of science:	WOS:000336266400012
Scopus:	2-s2.0-84891873467
Elibrary:	21862759
OpenAlex:	W1755783564

DB	Citing
Web of science	26
Scopus	28
Elibrary	24
OpenAlex	27