Isomerization of bicyclic terpene epoxides into allylic alcohols without changing of the initial structure Научная публикация
| Журнал |
Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169 |
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| Вых. Данные | Год: 2014, Том: 388, Номер: SI, Страницы: 162-166 Страниц : DOI: 10.1016/j.molcata.2013.09.016 | ||||||||
| Ключевые слова | Pinene epoxide; Verbenol epoxide; Isomerization; Titania; Gold | ||||||||
| Авторы |
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| Организации |
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Реферат:
A novel method of (1S,2R,3R,5R)-6,6-dimethy1-4-methylenebicyclo[3.1.1]heptane-2,3-diol synthesis, which is a valuable intermediate in the synthesis of a perspective potent anti-Parkinson drugs, in the presence of TiO2 was proposed. Catalytic activity of TiO2 in the bicyclic terpene epoxides isomerization to corresponding allylic alcohols without changing of the initial structure was demonstrated, contrary to titania-supported Au catalysts which promoted rearrangement with predominant formation of a cyclopentene alpha-hydroxy ketone. (C) 2013 Elsevier B.V. All rights reserved.
Библиографическая ссылка:
Demidova Y.S.
, Ardashov O.V.
, Simakova O.A.
, Simakova I.L.
, Volcho K.P.
, Salakhutdinov N.F.
, Murzin D.Y.
Isomerization of bicyclic terpene epoxides into allylic alcohols without changing of the initial structure
Journal of Molecular Catalysis A: Chemical. 2014. V.388. NSI. P.162-166. DOI: 10.1016/j.molcata.2013.09.016 WOS Scopus РИНЦ OpenAlex
Isomerization of bicyclic terpene epoxides into allylic alcohols without changing of the initial structure
Journal of Molecular Catalysis A: Chemical. 2014. V.388. NSI. P.162-166. DOI: 10.1016/j.molcata.2013.09.016 WOS Scopus РИНЦ OpenAlex
Даты:
| Опубликована в печати: | 1 июл. 2014 г. |
Идентификаторы БД:
| Web of science: | WOS:000337551800019 |
| Scopus: | 2-s2.0-84901324308 |
| РИНЦ: | 22049548 |
| OpenAlex: | W2066430198 |