Isomerization of bicyclic terpene epoxides into allylic alcohols without changing of the initial structure Full article
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Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169 |
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| Output data | Year: 2014, Volume: 388, Number: SI, Pages: 162-166 Pages count : DOI: 10.1016/j.molcata.2013.09.016 | ||||||||
| Tags | Pinene epoxide; Verbenol epoxide; Isomerization; Titania; Gold | ||||||||
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Abstract:
A novel method of (1S,2R,3R,5R)-6,6-dimethy1-4-methylenebicyclo[3.1.1]heptane-2,3-diol synthesis, which is a valuable intermediate in the synthesis of a perspective potent anti-Parkinson drugs, in the presence of TiO2 was proposed. Catalytic activity of TiO2 in the bicyclic terpene epoxides isomerization to corresponding allylic alcohols without changing of the initial structure was demonstrated, contrary to titania-supported Au catalysts which promoted rearrangement with predominant formation of a cyclopentene alpha-hydroxy ketone. (C) 2013 Elsevier B.V. All rights reserved.
Cite:
Demidova Y.S.
, Ardashov O.V.
, Simakova O.A.
, Simakova I.L.
, Volcho K.P.
, Salakhutdinov N.F.
, Murzin D.Y.
Isomerization of bicyclic terpene epoxides into allylic alcohols without changing of the initial structure
Journal of Molecular Catalysis A: Chemical. 2014. V.388. NSI. P.162-166. DOI: 10.1016/j.molcata.2013.09.016 WOS Scopus РИНЦ OpenAlex
Isomerization of bicyclic terpene epoxides into allylic alcohols without changing of the initial structure
Journal of Molecular Catalysis A: Chemical. 2014. V.388. NSI. P.162-166. DOI: 10.1016/j.molcata.2013.09.016 WOS Scopus РИНЦ OpenAlex
Dates:
| Published print: | Jul 1, 2014 |
Identifiers:
| Web of science: | WOS:000337551800019 |
| Scopus: | 2-s2.0-84901324308 |
| Elibrary: | 22049548 |
| OpenAlex: | W2066430198 |