Stepwise Selective Reduction of Polynitroarenes Using Isopropanol as a Source of Hydrogen in a Flow-Type Reactor in the Presence of Alumina

Stepwise Selective Reduction of Polynitroarenes Using Isopropanol as a Source of Hydrogen in a Flow-Type Reactor in the Presence of Alumina Научная публикация

Журнал

Journal of Flow Chemistry
ISSN: 2062-249X , E-ISSN: 2060-5587

Вых. Данные

Год: 2014, Том: 4, Номер: 3, Страницы: 113-117 Страниц : DOI: 10.1556/JFC-D-14-00004

Ключевые слова

hydrogen transfer; flow-type reactor; nitroarenes; amine; alumina

Авторы

Sivcev Vladislav P. ^1,2 , Volcho Konstantin P. ² , Salakhutdinov Nariman F. ² , Anikeev Vladimir I. ¹

Организации

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Siberian Branch, Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

Reduction of several polynitroarenes with isopropanol in a flow-type reactor in the presence of Al2O3 catalyst was studied. Temperature-controlled highly selective reduction of one, two, or three nitro groups in all the studied polynitroarenes proved to be feasible. N-alkylation of the reaction products was the predominant side reaction at high temperatures, except for the reduction of 2,7-dinitronaphthalene: in this case, a considerable amount of alkoxylated product was obtained. Benzo[c]cinnoline was the main product of reduction of 2,2'-dinitrobiphenyl.

Sivcev V.P. , Volcho K.P. , Salakhutdinov N.F. , Anikeev V.I.
Stepwise Selective Reduction of Polynitroarenes Using Isopropanol as a Source of Hydrogen in a Flow-Type Reactor in the Presence of Alumina
Journal of Flow Chemistry. 2014. V.4. N3. P.113-117. DOI: 10.1556/JFC-D-14-00004 WOS Scopus РИНЦ OpenAlex

Опубликована в печати:

17 сент. 2014 г.

Web of science:	WOS:000346133800003
Scopus:	2-s2.0-84907220157
РИНЦ:	23989016
OpenAlex:	W1969991601

БД	Цитирований
Web of science	7
Scopus	7
РИНЦ	6
OpenAlex	7