Stepwise Selective Reduction of Polynitroarenes Using Isopropanol as a Source of Hydrogen in a Flow-Type Reactor in the Presence of Alumina Full article
Journal |
Journal of Flow Chemistry
ISSN: 2062-249X , E-ISSN: 2060-5587 |
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Output data | Year: 2014, Volume: 4, Number: 3, Pages: 113-117 Pages count : DOI: 10.1556/JFC-D-14-00004 | ||||
Tags | hydrogen transfer; flow-type reactor; nitroarenes; amine; alumina | ||||
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Abstract:
Reduction of several polynitroarenes with isopropanol in a flow-type reactor in the presence of Al2O3 catalyst was studied. Temperature-controlled highly selective reduction of one, two, or three nitro groups in all the studied polynitroarenes proved to be feasible. N-alkylation of the reaction products was the predominant side reaction at high temperatures, except for the reduction of 2,7-dinitronaphthalene: in this case, a considerable amount of alkoxylated product was obtained. Benzo[c]cinnoline was the main product of reduction of 2,2'-dinitrobiphenyl.
Cite:
Sivcev V.P.
, Volcho K.P.
, Salakhutdinov N.F.
, Anikeev V.I.
Stepwise Selective Reduction of Polynitroarenes Using Isopropanol as a Source of Hydrogen in a Flow-Type Reactor in the Presence of Alumina
Journal of Flow Chemistry. 2014. V.4. N3. P.113-117. DOI: 10.1556/JFC-D-14-00004 WOS Scopus РИНЦ OpenAlex
Stepwise Selective Reduction of Polynitroarenes Using Isopropanol as a Source of Hydrogen in a Flow-Type Reactor in the Presence of Alumina
Journal of Flow Chemistry. 2014. V.4. N3. P.113-117. DOI: 10.1556/JFC-D-14-00004 WOS Scopus РИНЦ OpenAlex
Dates:
Published print: | Sep 17, 2014 |
Identifiers:
Web of science: | WOS:000346133800003 |
Scopus: | 2-s2.0-84907220157 |
Elibrary: | 23989016 |
OpenAlex: | W1969991601 |