Sciact
  • EN
  • RU

Stepwise Selective Reduction of Polynitroarenes Using Isopropanol as a Source of Hydrogen in a Flow-Type Reactor in the Presence of Alumina Full article

Journal Journal of Flow Chemistry
ISSN: 2062-249X , E-ISSN: 2060-5587
Output data Year: 2014, Volume: 4, Number: 3, Pages: 113-117 Pages count : DOI: 10.1556/JFC-D-14-00004
Tags hydrogen transfer; flow-type reactor; nitroarenes; amine; alumina
Authors Sivcev Vladislav P. 1,2 , Volcho Konstantin P. 2 , Salakhutdinov Nariman F. 2 , Anikeev Vladimir I. 1
Affiliations
1 (Данные Web of science) Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Novosibirsk 630090, Russia
2 (Данные Web of science) Russian Acad Sci, Siberian Branch, Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

Abstract: Reduction of several polynitroarenes with isopropanol in a flow-type reactor in the presence of Al2O3 catalyst was studied. Temperature-controlled highly selective reduction of one, two, or three nitro groups in all the studied polynitroarenes proved to be feasible. N-alkylation of the reaction products was the predominant side reaction at high temperatures, except for the reduction of 2,7-dinitronaphthalene: in this case, a considerable amount of alkoxylated product was obtained. Benzo[c]cinnoline was the main product of reduction of 2,2'-dinitrobiphenyl.
Cite: Sivcev V.P. , Volcho K.P. , Salakhutdinov N.F. , Anikeev V.I.
Stepwise Selective Reduction of Polynitroarenes Using Isopropanol as a Source of Hydrogen in a Flow-Type Reactor in the Presence of Alumina
Journal of Flow Chemistry. 2014. V.4. N3. P.113-117. DOI: 10.1556/JFC-D-14-00004 WOS Scopus РИНЦ OpenAlex
Dates:
Published print: Sep 17, 2014
Identifiers:
Web of science: WOS:000346133800003
Scopus: 2-s2.0-84907220157
Elibrary: 23989016
OpenAlex: W1969991601
Citing:
DB Citing
Web of science 6
Scopus 6
Elibrary 6
OpenAlex 6
Altmetrics: