Abstract: 15,16-Epoxy-16-(3-trimethylsiloxybuta-1,3-dien-1-yl)labdanoids were synthesized, and their reactions with cyclic dienophiles (1,4-benzoquinone, 1,4-toluquinone, 2-bromo-6-methyl-1,4-benzoquinone, and N-methylmaleimide) were studied. The reactions with unsymmetrically substituted benzoquinones were not selective. Methods for the preparation of hybrid compounds containing furan diterpenoid and substituted naphthoquinone, octahydroisoindoletrione, or hexahydroisoindoledione fragments were proposed.

Cite: Mironov M.E. , Shul'ts E.E. , Shakirov M.M. , Kharitonov Y.V. , Tolstikov G.A.
Synthetic transformations of higher terpenoids: XXVIII. Diels-Alder reactions of 16-(trimethylsiloxybutadienyl) labdanoids
Russian Journal of Organic Chemistry. 2012. V.48. N6. P.840-850. DOI: 10.1134/S1070428012060164 WOS Scopus РИНЦ OpenAlex

Original: Миронов М.Е. , Шульц Э.Э. , Шакиров М.М. , Харитонов Ю.В. , Толстиков Г.А.
Синтетические трансформации высших терпеноидов xxviii.* диеновый синтез с участием 16-(триметилсилоксибутадиенил)лабданоидов
Журнал органической химии (RUSS J ORG CHEM+). 2012. Т.48. №6. С.842-852. РИНЦ

Dates:

Published print:	Jun 1, 2012
Published online:	Jul 5, 2012

Identifiers:

Web of science:	WOS:000306571600016
Scopus:	2-s2.0-84865495064
Elibrary:	20471723
OpenAlex:	W2083554821

Citing:

DB	Citing
Web of science	5
Scopus	4
Elibrary	4
OpenAlex	4

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