Reaction of 3,3 '-bis(2-phenyl-5,5-dimethyl-4-oxopyrrolinylidene) 1,1 '-dioxide with the methoxide anion

Reaction of 3,3 '-bis(2-phenyl-5,5-dimethyl-4-oxopyrrolinylidene) 1,1 '-dioxide with the methoxide anion Научная публикация

Журнал

Mendeleev Communications
ISSN: 0959-9436

Вых. Данные

Год: 2012, Том: 22, Номер: 6, Страницы: 327-329 Страниц : 3 DOI: 10.1016/j.mencom.2012.11.017

Авторы

Khalfina Irina A. ¹ , Vasilieva Nadezhda V. ¹ , Irtegova Irina G. ¹ , Reznikov Vladimir A. ¹ , Shundrin Leonid A. ¹

Организации

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

The title reaction in methanol includes the addition of MeO- to the carbonyl group of a pyrrolinone ring followed by ring opening, and the one-electron oxidation of the formed anion results in the formation of a stable nitroxide, as found by cyclic voltammetry and EPR spectroscopy.

Khalfina I.A. , Vasilieva N.V. , Irtegova I.G. , Reznikov V.A. , Shundrin L.A.
Reaction of 3,3 '-bis(2-phenyl-5,5-dimethyl-4-oxopyrrolinylidene) 1,1 '-dioxide with the methoxide anion
Mendeleev Communications. 2012. V.22. N6. P.327-329. DOI: 10.1016/j.mencom.2012.11.017 WOS Scopus РИНЦ РИНЦ OpenAlex

Опубликована в печати:

1 нояб. 2012 г.

Web of science:	WOS:000312919100017
Scopus:	2-s2.0-84870343361
РИНЦ:	20494173 \| 18933962
OpenAlex:	W2029253051

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