Reductive activation of arenes 21. Reaction of products of two-electron reduction of arenecarbonitriles by alkali metals in liquid ammonia with bromo- and dibromoalkanes

Reductive activation of arenes 21. Reaction of products of two-electron reduction of arenecarbonitriles by alkali metals in liquid ammonia with bromo- and dibromoalkanes Научная публикация

Журнал

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Вых. Данные

Год: 2006, Том: 55, Номер: 6, Страницы: 981-986 Страниц : DOI: 10.1007/s11172-006-0366-0

Ключевые слова

aromatic nitrites; reductive alkylation; cyanocyclohexadienyl anions; l-alkyl-l-cyanocyclohexa-2,5-dienes; 1-(omega-bromoalkyl)-l-cyanocyclohexa-2,5-dienes

Авторы

Vaganova T. A. , Panteleeva E. V. , Yuferov P. S. , Rebitva Yu. V. , Shteingarts V. D.

Организации

1	(Данные Web of science) Russian Acad Sci, NN Vorozhtsov Novosbirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia
3	(Данные Web of science) Novosibirsk State Pedagog Univ, Novosibirsk 630126, Russia

Reductive alkylation of benzonitrile, ortho-, meta-, para-tolunitriles, and 1-naphthonitrile by sequential action of alkali metal and alkyl bromide in liquid ammonia results in corresponding alkylarenes and 1-alkyl-1-cyanocyclohexa-2,5-dienes. The experimental conditions for target synthesis of the specified products are found. A method of synthesis of 1-(omega-bromoalkyl)-1-cyanocyclohexa-2,5-dienes based on the interaction of two-electronic reduction products of aromatic nitriles with alpha,omega-dibromoalkanes Br(CH2)(n)Br (n = 3-5) is developed.

Vaganova T.A. , Panteleeva E.V. , Yuferov P.S. , Rebitva Y.V. , Shteingarts V.D.
Reductive activation of arenes 21. Reaction of products of two-electron reduction of arenecarbonitriles by alkali metals in liquid ammonia with bromo- and dibromoalkanes
Russian Chemical Bulletin. 2006. V.55. N6. P.981-986. DOI: 10.1007/s11172-006-0366-0 WOS Scopus РИНЦ OpenAlex

Опубликована в печати:

1 июн. 2006 г.

Web of science:	WOS:000242652000008
Scopus:	2-s2.0-33750718171
РИНЦ:	13524130
OpenAlex:	W2126508608

БД	Цитирований
Web of science	3
Scopus	1
РИНЦ	1
OpenAlex	2