Reductive activation of arenes 21. Reaction of products of two-electron reduction of arenecarbonitriles by alkali metals in liquid ammonia with bromo- and dibromoalkanes Full article
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Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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| Output data | Year: 2006, Volume: 55, Number: 6, Pages: 981-986 Pages count : DOI: 10.1007/s11172-006-0366-0 | ||||||
| Tags | aromatic nitrites; reductive alkylation; cyanocyclohexadienyl anions; l-alkyl-l-cyanocyclohexa-2,5-dienes; 1-(omega-bromoalkyl)-l-cyanocyclohexa-2,5-dienes | ||||||
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Abstract:
Reductive alkylation of benzonitrile, ortho-, meta-, para-tolunitriles, and 1-naphthonitrile by sequential action of alkali metal and alkyl bromide in liquid ammonia results in corresponding alkylarenes and 1-alkyl-1-cyanocyclohexa-2,5-dienes. The experimental conditions for target synthesis of the specified products are found. A method of synthesis of 1-(omega-bromoalkyl)-1-cyanocyclohexa-2,5-dienes based on the interaction of two-electronic reduction products of aromatic nitriles with alpha,omega-dibromoalkanes Br(CH2)(n)Br (n = 3-5) is developed.
Cite:
Vaganova T.A.
, Panteleeva E.V.
, Yuferov P.S.
, Rebitva Y.V.
, Shteingarts V.D.
Reductive activation of arenes 21. Reaction of products of two-electron reduction of arenecarbonitriles by alkali metals in liquid ammonia with bromo- and dibromoalkanes
Russian Chemical Bulletin. 2006. V.55. N6. P.981-986. DOI: 10.1007/s11172-006-0366-0 WOS Scopus РИНЦ OpenAlex
Reductive activation of arenes 21. Reaction of products of two-electron reduction of arenecarbonitriles by alkali metals in liquid ammonia with bromo- and dibromoalkanes
Russian Chemical Bulletin. 2006. V.55. N6. P.981-986. DOI: 10.1007/s11172-006-0366-0 WOS Scopus РИНЦ OpenAlex
Dates:
| Published print: | Jun 1, 2006 |
Identifiers:
| Web of science: | WOS:000242652000008 |
| Scopus: | 2-s2.0-33750718171 |
| Elibrary: | 13524130 |
| OpenAlex: | W2126508608 |