Synthesis and molecular and crystal structure of 3-(1-amino-2,2,2-trifluoroethylidene)-2-imino-1,1,4,5,6,7-hexafluoroindan and its N-methyl and N,N '-dimethyl derivatives Научная публикация
| Журнал |
Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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| Вых. Данные | Год: 2006, Том: 47, Номер: 3, Страницы: 519-526 Страниц : 8 DOI: 10.1007/s10947-006-0331-7 | ||
| Ключевые слова | polyfluorinated enaminoimines; indan; indene; synthesis; structure; X-ray diffraction analysis; tautomers; quantum chemical calculations | ||
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Реферат:
3-(2-Amino-2,2,2-trifluoroethylidene)-2-imino-1,1,4,5,6,7-hexafluoroindan (2) and its N-methyl and N,N'dimethyl derivatives were synthesized by the reaction of perforo-1-ethylideneindan with ammonia and methylamine or by methylation of compound 2 with dimethylsulfate. Single crystals were grown and the molecular and crystal structure of the emaninoimine products was investigated. The density functional theory (DFT) quantum chemical calculations were performed to determine possible tautomeric equilibrium of the emaninoimine products.
Библиографическая ссылка:
Karpov V.M.
, Platonov V.E.
, Rybalova T.V.
, Gatilov Y.V.
Synthesis and molecular and crystal structure of 3-(1-amino-2,2,2-trifluoroethylidene)-2-imino-1,1,4,5,6,7-hexafluoroindan and its N-methyl and N,N '-dimethyl derivatives
Journal of Structural Chemistry. 2006. V.47. N3. P.519-526. DOI: 10.1007/s10947-006-0331-7 WOS Scopus РИНЦ OpenAlex
Synthesis and molecular and crystal structure of 3-(1-amino-2,2,2-trifluoroethylidene)-2-imino-1,1,4,5,6,7-hexafluoroindan and its N-methyl and N,N '-dimethyl derivatives
Journal of Structural Chemistry. 2006. V.47. N3. P.519-526. DOI: 10.1007/s10947-006-0331-7 WOS Scopus РИНЦ OpenAlex
Даты:
| Опубликована в печати: | 1 мая 2006 г. |
Идентификаторы БД:
| Web of science: | WOS:000242330700018 |
| Scopus: | 2-s2.0-33750726084 |
| РИНЦ: | 13528876 |
| OpenAlex: | W1998471883 |