Synthesis and molecular and crystal structure of 3-(1-amino-2,2,2-trifluoroethylidene)-2-imino-1,1,4,5,6,7-hexafluoroindan and its N-methyl and N,N '-dimethyl derivatives Full article
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Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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| Output data | Year: 2006, Volume: 47, Number: 3, Pages: 519-526 Pages count : 8 DOI: 10.1007/s10947-006-0331-7 | ||
| Tags | polyfluorinated enaminoimines; indan; indene; synthesis; structure; X-ray diffraction analysis; tautomers; quantum chemical calculations | ||
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Abstract:
3-(2-Amino-2,2,2-trifluoroethylidene)-2-imino-1,1,4,5,6,7-hexafluoroindan (2) and its N-methyl and N,N'dimethyl derivatives were synthesized by the reaction of perforo-1-ethylideneindan with ammonia and methylamine or by methylation of compound 2 with dimethylsulfate. Single crystals were grown and the molecular and crystal structure of the emaninoimine products was investigated. The density functional theory (DFT) quantum chemical calculations were performed to determine possible tautomeric equilibrium of the emaninoimine products.
Cite:
Karpov V.M.
, Platonov V.E.
, Rybalova T.V.
, Gatilov Y.V.
Synthesis and molecular and crystal structure of 3-(1-amino-2,2,2-trifluoroethylidene)-2-imino-1,1,4,5,6,7-hexafluoroindan and its N-methyl and N,N '-dimethyl derivatives
Journal of Structural Chemistry. 2006. V.47. N3. P.519-526. DOI: 10.1007/s10947-006-0331-7 WOS Scopus РИНЦ OpenAlex
Synthesis and molecular and crystal structure of 3-(1-amino-2,2,2-trifluoroethylidene)-2-imino-1,1,4,5,6,7-hexafluoroindan and its N-methyl and N,N '-dimethyl derivatives
Journal of Structural Chemistry. 2006. V.47. N3. P.519-526. DOI: 10.1007/s10947-006-0331-7 WOS Scopus РИНЦ OpenAlex
Dates:
| Published print: | May 1, 2006 |
Identifiers:
| Web of science: | WOS:000242330700018 |
| Scopus: | 2-s2.0-33750726084 |
| Elibrary: | 13528876 |
| OpenAlex: | W1998471883 |