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Binuclear copper(II) complexes with (1R*,4S*)-l-N-morpholino-n-menth-8-en-2-one E-oxime: Synthesis, structure, and magnetic properties Научная публикация

Журнал Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284
Вых. Данные Год: 2002, Том: 28, Номер: 11, Страницы: 780-788 Страниц : 9 DOI: 10.1023/A:1021106914937
Авторы Larionov SV , Savel'eva ZA , Romanenko GV , Tkachev AV , Ikorskii VN , Boguslavskii EG
Организации
1 (Данные Web of science) Russian Acad Sci, Siberian Div, Inst Inorgan Chem, Novosibirsk 630090, Russia
2 (Данные Web of science) Russian Acad Sci, Siberian Div, Novosibirsk Organ Chem Inst, Novosibirsk 630090, Russia

Реферат: Copper(II) complexes with (1R*,4S*)-1-N-morpholino-n-menth-8-en-4-one (HL), namely, [Cu-2(HL)(2)Cl-4] (I) and [Cu-2(HL)LCl3] . CH3CN (II), were synthesized and characterized by X-ray diffraction analysis, magnetic susceptibility, and EPR methods. The complexes have binuclear structures. In compound I, the coordination polyhedron of CuCl3N2 is a square pyramid in planar Cu2Cl2 metal cycle; the exchange couplings of unpaired electrons of Cu(II) ions are weak. Complex II incorporates polyhedra of CuCl2N2 (flattened tetrahedron) and of CuCl2N2O (trigonal bipyramid). The Cu2ClNO metal cycle is nonplanar with antiferromagnetic exchange coupling and exchange parameter -2J = 182 cm(-1). The EPR spectrum of compound I are analyzed.
Библиографическая ссылка: Larionov S. , Savel'eva Z. , Romanenko G. , Tkachev A. , Ikorskii V. , Boguslavskii E.
Binuclear copper(II) complexes with (1R*,4S*)-l-N-morpholino-n-menth-8-en-2-one E-oxime: Synthesis, structure, and magnetic properties
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2002. V.28. N11. P.780-788. DOI: 10.1023/A:1021106914937 WOS Scopus РИНЦ OpenAlex
Идентификаторы БД:
Web of science: WOS:000179652500007
Scopus: 2-s2.0-1842479654
РИНЦ: 31339559
OpenAlex: W310473400
Цитирование в БД:
БД Цитирований
Web of science 2
Scopus 2
OpenAlex 7
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