Binuclear copper(II) complexes with (1R*,4S*)-l-N-morpholino-n-menth-8-en-2-one E-oxime: Synthesis, structure, and magnetic properties Full article
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Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284 |
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| Output data | Year: 2002, Volume: 28, Number: 11, Pages: 780-788 Pages count : 9 DOI: 10.1023/A:1021106914937 | ||||
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Abstract:
Copper(II) complexes with (1R*,4S*)-1-N-morpholino-n-menth-8-en-4-one (HL), namely, [Cu-2(HL)(2)Cl-4] (I) and [Cu-2(HL)LCl3] . CH3CN (II), were synthesized and characterized by X-ray diffraction analysis, magnetic susceptibility, and EPR methods. The complexes have binuclear structures. In compound I, the coordination polyhedron of CuCl3N2 is a square pyramid in planar Cu2Cl2 metal cycle; the exchange couplings of unpaired electrons of Cu(II) ions are weak. Complex II incorporates polyhedra of CuCl2N2 (flattened tetrahedron) and of CuCl2N2O (trigonal bipyramid). The Cu2ClNO metal cycle is nonplanar with antiferromagnetic exchange coupling and exchange parameter -2J = 182 cm(-1). The EPR spectrum of compound I are analyzed.
Cite:
Larionov S.
, Savel'eva Z.
, Romanenko G.
, Tkachev A.
, Ikorskii V.
, Boguslavskii E.
Binuclear copper(II) complexes with (1R*,4S*)-l-N-morpholino-n-menth-8-en-2-one E-oxime: Synthesis, structure, and magnetic properties
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2002. V.28. N11. P.780-788. DOI: 10.1023/A:1021106914937 WOS Scopus РИНЦ OpenAlex
Binuclear copper(II) complexes with (1R*,4S*)-l-N-morpholino-n-menth-8-en-2-one E-oxime: Synthesis, structure, and magnetic properties
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2002. V.28. N11. P.780-788. DOI: 10.1023/A:1021106914937 WOS Scopus РИНЦ OpenAlex
Identifiers:
| Web of science: | WOS:000179652500007 |
| Scopus: | 2-s2.0-1842479654 |
| Elibrary: | 31339559 |
| OpenAlex: | W310473400 |