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Reductive transformations of organofluorine compounds: III. Hydrodefluorination of perfluoroalkylbenzenes effected by Zn(Cu). The unusual behavior of compounds containing perfluorinated tert-butyl group Научная публикация

Журнал Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393
Вых. Данные Год: 2001, Том: 37, Номер: 4, Страницы: 517-522 Страниц : 6 DOI: 10.1023/A:1012429802321
Авторы Krasnov B.I. 1 , Platonov V.E. 1
Организации
1 (Данные Web of science) Russian Acad Sci, Siberian Div, Vorozhstov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

Реферат: Perfluoroalkylbenzenes under a treatment of a system Zn(Cu)-DMF-H2O-electrolyte give rise in high yield to products of fluorine substitution by hydrogen in position 4. In perfluoro-tert-butylbenzene are substituted by hydrogen the fluorine atoms in positions 2 and 4; here the DMF-water ratio affects the regioselectivity of the process. In the perfluoro-4-tert-butyltoluene is mainly substituted the fluorine in the ortho-position to the C(CF3)(3) group.
Библиографическая ссылка: Krasnov B.I. , Platonov V.E.
Reductive transformations of organofluorine compounds: III. Hydrodefluorination of perfluoroalkylbenzenes effected by Zn(Cu). The unusual behavior of compounds containing perfluorinated tert-butyl group
Russian Journal of Organic Chemistry. 2001. V.37. N4. P.517-522. DOI: 10.1023/A:1012429802321 WOS Scopus РИНЦ OpenAlex
Идентификаторы БД:
Web of science: WOS:000170630600008
Scopus: 2-s2.0-0035537141
РИНЦ: 13365445
OpenAlex: W2996048809
Цитирование в БД:
БД Цитирований
Web of science 8
Scopus 8
РИНЦ 6
OpenAlex 10
Альметрики: