Reductive transformations of organofluorine compounds: III. Hydrodefluorination of perfluoroalkylbenzenes effected by Zn(Cu). The unusual behavior of compounds containing perfluorinated tert-butyl group Full article
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Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393 |
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| Output data | Year: 2001, Volume: 37, Number: 4, Pages: 517-522 Pages count : 6 DOI: 10.1023/A:1012429802321 | ||
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Abstract:
Perfluoroalkylbenzenes under a treatment of a system Zn(Cu)-DMF-H2O-electrolyte give rise in high yield to products of fluorine substitution by hydrogen in position 4. In perfluoro-tert-butylbenzene are substituted by hydrogen the fluorine atoms in positions 2 and 4; here the DMF-water ratio affects the regioselectivity of the process. In the perfluoro-4-tert-butyltoluene is mainly substituted the fluorine in the ortho-position to the C(CF3)(3) group.
Cite:
Krasnov B.I.
, Platonov V.E.
Reductive transformations of organofluorine compounds: III. Hydrodefluorination of perfluoroalkylbenzenes effected by Zn(Cu). The unusual behavior of compounds containing perfluorinated tert-butyl group
Russian Journal of Organic Chemistry. 2001. V.37. N4. P.517-522. DOI: 10.1023/A:1012429802321 WOS Scopus РИНЦ OpenAlex
Reductive transformations of organofluorine compounds: III. Hydrodefluorination of perfluoroalkylbenzenes effected by Zn(Cu). The unusual behavior of compounds containing perfluorinated tert-butyl group
Russian Journal of Organic Chemistry. 2001. V.37. N4. P.517-522. DOI: 10.1023/A:1012429802321 WOS Scopus РИНЦ OpenAlex
Identifiers:
| Web of science: | WOS:000170630600008 |
| Scopus: | 2-s2.0-0035537141 |
| Elibrary: | 13365445 |
| OpenAlex: | W2996048809 |