Syntheses and crystal structure of bridged Os-3-clusters with chiral 3-carane-type ligands Научная публикация
| Журнал |
Journal of Organometallic Chemistry
ISSN: 0022-328X |
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| Вых. Данные | Год: 2000, Том: 604, Номер: 1, Страницы: 1-6 Страниц : DOI: 10.1016/S0022-328X(00)00153-4 | ||||
| Ключевые слова | Os-3 clusters; osmium carbonyl clusters; chiral ligand; terpenoid | ||||
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Реферат:
Reaction of (mu-H)(2)Os-3(CO)(10) cluster with (1S,3S,6R)-3-dimethylaminocarane-4-one E-oxime results in loss of dimethylamino group and formation of (mu-H)Os-3(CO)(10)(mu-ON=C drop) cluster (43%). Treatment of cluster Os-3(CO)(11)(N=CCH3) with (1S,3S,6R)-3-mercaptocaran-4-one E-oxime gives cluster (mu-H)Os-3(CO)(10)(mu-S-...) in 86%, whose structure was proved by X-ray single crystal analysis. Decarbonylation of the later compound with (CH3)(3)NO leads to a diastereomeric mixture of (mu-H)Os-3(CO)(9)(mu,eta(2)-(S,N)-...) clusters in 64% yield. (C) 2000 Published by Elsevier Science S.A. All rights reserved.
Библиографическая ссылка:
Maksakov V.
, Kirin V.
, Petukhov P.
, Rybalova T.
, Gatilov Y.
, Tkachev A.
Syntheses and crystal structure of bridged Os-3-clusters with chiral 3-carane-type ligands
Journal of Organometallic Chemistry. 2000. V.604. N1. P.1-6. DOI: 10.1016/S0022-328X(00)00153-4 WOS Scopus РИНЦ OpenAlex
Syntheses and crystal structure of bridged Os-3-clusters with chiral 3-carane-type ligands
Journal of Organometallic Chemistry. 2000. V.604. N1. P.1-6. DOI: 10.1016/S0022-328X(00)00153-4 WOS Scopus РИНЦ OpenAlex
Даты:
| Опубликована в печати: | 1 июн. 2000 г. |
Идентификаторы БД:
| Web of science: | WOS:000088339500001 |
| Scopus: | 2-s2.0-0001924049 |
| РИНЦ: | 13346620 |
| OpenAlex: | W2111000824 |