Syntheses and crystal structure of bridged Os-3-clusters with chiral 3-carane-type ligands

Syntheses and crystal structure of bridged Os-3-clusters with chiral 3-carane-type ligands Full article

Journal

Journal of Organometallic Chemistry
ISSN: 0022-328X

Output data

Year: 2000, Volume: 604, Number: 1, Pages: 1-6 Pages count : DOI: 10.1016/S0022-328X(00)00153-4

Tags

Os-3 clusters; osmium carbonyl clusters; chiral ligand; terpenoid

Authors

Maksakov VA , Kirin VP , Petukhov PA , Rybalova TV , Gatilov YV , Tkachev AV

Affiliations

1	(Данные Web of science) Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Inst Inorgan Chem, Novosibirsk 630090, Russia

Reaction of (mu-H)(2)Os-3(CO)(10) cluster with (1S,3S,6R)-3-dimethylaminocarane-4-one E-oxime results in loss of dimethylamino group and formation of (mu-H)Os-3(CO)(10)(mu-ON=C drop) cluster (43%). Treatment of cluster Os-3(CO)(11)(N=CCH3) with (1S,3S,6R)-3-mercaptocaran-4-one E-oxime gives cluster (mu-H)Os-3(CO)(10)(mu-S-...) in 86%, whose structure was proved by X-ray single crystal analysis. Decarbonylation of the later compound with (CH3)(3)NO leads to a diastereomeric mixture of (mu-H)Os-3(CO)(9)(mu,eta(2)-(S,N)-...) clusters in 64% yield. (C) 2000 Published by Elsevier Science S.A. All rights reserved.

Maksakov V. , Kirin V. , Petukhov P. , Rybalova T. , Gatilov Y. , Tkachev A.
Syntheses and crystal structure of bridged Os-3-clusters with chiral 3-carane-type ligands
Journal of Organometallic Chemistry. 2000. V.604. N1. P.1-6. DOI: 10.1016/S0022-328X(00)00153-4 WOS Scopus РИНЦ OpenAlex

Published print:

Jun 1, 2000

Web of science:	WOS:000088339500001
Scopus:	2-s2.0-0001924049
Elibrary:	13346620
OpenAlex:	W2111000824

DB	Citing
Web of science	6
Scopus	8
Elibrary	8
OpenAlex	7