Conformational dynamics of some short-chain biradicals in solutions | Sciact

Conformational dynamics of some short-chain biradicals in solutions Научная публикация

Журнал

Applied Magnetic Resonance
ISSN: 0937-9347 , E-ISSN: 1613-7507

Вых. Данные

Год: 2000, Том: 19, Номер: 2, Страницы: 187-196 Страниц : 10 DOI: 10.1007/BF03162273

Авторы

Grampp G. ³ , Landgraf S. ³ , Grigor'ev I.A. ² , Shapiro A.B. ¹ , Kokorin A.I. ¹

Организации

1	(Данные Web of science) Russian Acad Sci, NN Semenov Chem Phys Inst, Moscow 117977, Russia
2	(Данные Web of science) Russian Acad Sci, Inst Organ Chem, Novosibirsk 630090, Russia
3	(Данные Web of science) Graz Univ Technol, Inst Phys & Theoret Chem, A-8010 Graz, Austria

Intramolecular electron spin exchange, as a function of temperature and the solvent nature has been studied by X-band electron paramagnetic resonance (EPR) spectroscopy in five short-chain flexible nitroxide biradicals. Certain thermodynamic parameters of the conformational rearrangements were calculated from the EPR spectra. The process of spin exchange in short flexible biradicals has some peculiarities in comparison with that in long-chain molecules.

Grampp G. , Landgraf S. , Grigor'ev I.A. , Shapiro A.B. , Kokorin A.I.
Conformational dynamics of some short-chain biradicals in solutions
Applied Magnetic Resonance. 2000. V.19. N2. P.187-196. DOI: 10.1007/BF03162273 WOS Scopus OpenAlex

Опубликована в печати:

1 июн. 2000 г.

Web of science:	WOS:000166495300004
Scopus:	2-s2.0-0034549279
OpenAlex:	W2127918425

БД	Цитирований
Web of science	13
Scopus	13
OpenAlex	13