Conformational dynamics of some short-chain biradicals in solutions

Conformational dynamics of some short-chain biradicals in solutions Full article

Journal

Applied Magnetic Resonance
ISSN: 0937-9347 , E-ISSN: 1613-7507

Output data

Year: 2000, Volume: 19, Number: 2, Pages: 187-196 Pages count : 10 DOI: 10.1007/BF03162273

Authors

Grampp G. ³ , Landgraf S. ³ , Grigor'ev I.A. ² , Shapiro A.B. ¹ , Kokorin A.I. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, NN Semenov Chem Phys Inst, Moscow 117977, Russia
2	(Данные Web of science) Russian Acad Sci, Inst Organ Chem, Novosibirsk 630090, Russia
3	(Данные Web of science) Graz Univ Technol, Inst Phys & Theoret Chem, A-8010 Graz, Austria

Intramolecular electron spin exchange, as a function of temperature and the solvent nature has been studied by X-band electron paramagnetic resonance (EPR) spectroscopy in five short-chain flexible nitroxide biradicals. Certain thermodynamic parameters of the conformational rearrangements were calculated from the EPR spectra. The process of spin exchange in short flexible biradicals has some peculiarities in comparison with that in long-chain molecules.

Grampp G. , Landgraf S. , Grigor'ev I.A. , Shapiro A.B. , Kokorin A.I.
Conformational dynamics of some short-chain biradicals in solutions
Applied Magnetic Resonance. 2000. V.19. N2. P.187-196. DOI: 10.1007/BF03162273 WOS Scopus OpenAlex

Published print:

Jun 1, 2000

Web of science:	WOS:000166495300004
Scopus:	2-s2.0-0034549279
OpenAlex:	W2127918425

DB	Citing
Web of science	13
Scopus	13
OpenAlex	13