Preparation of halogeno(pentafluorophenyl)silanes (C6F5)(n)SiX4-n (X = F, Cl and Br; n = 2, 3) from pentafluorophenyl(phenyl)silanes (C6F5)(n)SiPh4-n Научная публикация
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Journal of Organometallic Chemistry
ISSN: 0022-328X |
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| Вых. Данные | Год: 1998, Том: 568, Номер: 1-2, Страницы: 233-240 Страниц : 8 DOI: 10.1016/S0022-328X(98)00720-7 | ||||
| Ключевые слова | silanes; electrophilic substitution; silicon | ||||
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Реферат:
Halogeno(pentafluorophenyl)silanes (C6F5)nSiX(4-n) (X = F, Cl and Br; n = 2, 3) were prepared in good yields from the corresponding phenylsilanes (C6F5)(n)SiPh4-n by reactions with the electrophiles aHF, FSO3H, HCl-AlCl, or with AlX3 (X = Cl, Br)-halogenated hydrocarbons. The relative leaving ability of the organyl groups (C6F5, C6H5, Me) bonded to the silicon atom and the strength of the electrophilic reagent are discussed. (C) 1998 Elsevier Science S.A. All rights reserved.
Библиографическая ссылка:
Frohn H.-J.
, Lewin A.
, Bardin V.V.
Preparation of halogeno(pentafluorophenyl)silanes (C6F5)(n)SiX4-n (X = F, Cl and Br; n = 2, 3) from pentafluorophenyl(phenyl)silanes (C6F5)(n)SiPh4-n
Journal of Organometallic Chemistry. 1998. V.568. N1-2. P.233-240. DOI: 10.1016/S0022-328X(98)00720-7 WOS Scopus РИНЦ OpenAlex
Preparation of halogeno(pentafluorophenyl)silanes (C6F5)(n)SiX4-n (X = F, Cl and Br; n = 2, 3) from pentafluorophenyl(phenyl)silanes (C6F5)(n)SiPh4-n
Journal of Organometallic Chemistry. 1998. V.568. N1-2. P.233-240. DOI: 10.1016/S0022-328X(98)00720-7 WOS Scopus РИНЦ OpenAlex
Даты:
| Опубликована в печати: | 1 окт. 1998 г. |
Идентификаторы БД:
| Web of science: | WOS:000076317500025 |
| Scopus: | 2-s2.0-0039401911 |
| РИНЦ: | 13303458 |
| OpenAlex: | W2050922019 |