Preparation of halogeno(pentafluorophenyl)silanes (C6F5)(n)SiX4-n (X = F, Cl and Br; n = 2, 3) from pentafluorophenyl(phenyl)silanes (C6F5)(n)SiPh4-n Full article
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Journal of Organometallic Chemistry
ISSN: 0022-328X |
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| Output data | Year: 1998, Volume: 568, Number: 1-2, Pages: 233-240 Pages count : 8 DOI: 10.1016/S0022-328X(98)00720-7 | ||||
| Tags | silanes; electrophilic substitution; silicon | ||||
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Abstract:
Halogeno(pentafluorophenyl)silanes (C6F5)nSiX(4-n) (X = F, Cl and Br; n = 2, 3) were prepared in good yields from the corresponding phenylsilanes (C6F5)(n)SiPh4-n by reactions with the electrophiles aHF, FSO3H, HCl-AlCl, or with AlX3 (X = Cl, Br)-halogenated hydrocarbons. The relative leaving ability of the organyl groups (C6F5, C6H5, Me) bonded to the silicon atom and the strength of the electrophilic reagent are discussed. (C) 1998 Elsevier Science S.A. All rights reserved.
Cite:
Frohn H.-J.
, Lewin A.
, Bardin V.V.
Preparation of halogeno(pentafluorophenyl)silanes (C6F5)(n)SiX4-n (X = F, Cl and Br; n = 2, 3) from pentafluorophenyl(phenyl)silanes (C6F5)(n)SiPh4-n
Journal of Organometallic Chemistry. 1998. V.568. N1-2. P.233-240. DOI: 10.1016/S0022-328X(98)00720-7 WOS Scopus РИНЦ OpenAlex
Preparation of halogeno(pentafluorophenyl)silanes (C6F5)(n)SiX4-n (X = F, Cl and Br; n = 2, 3) from pentafluorophenyl(phenyl)silanes (C6F5)(n)SiPh4-n
Journal of Organometallic Chemistry. 1998. V.568. N1-2. P.233-240. DOI: 10.1016/S0022-328X(98)00720-7 WOS Scopus РИНЦ OpenAlex
Dates:
| Published print: | Oct 1, 1998 |
Identifiers:
| Web of science: | WOS:000076317500025 |
| Scopus: | 2-s2.0-0039401911 |
| Elibrary: | 13303458 |
| OpenAlex: | W2050922019 |