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Synthesis and spectroscopic studies of furan-bridged polyazamacrocycles through 15,16-bis((prop-2-ynylamino)methyl)labdatriene transformations Научная публикация

Журнал Journal of Inclusion Phenomena and Macrocyclic Chemistry
ISSN: 0923-0750 , E-ISSN: 1573-1111
Вых. Данные Год: 2020, Том: 96, Номер: 3-4, Страницы: 245-250 Страниц : 6 DOI: 10.1007/s10847-019-00965-z
Ключевые слова Macroheterocycles; Diterpenoids; Furanolabdanoid dialkynes; Diazides; CuAAC reaction; Zinc ion
Авторы Brusentzeva Olga, I 1 , Kharitonov Yurii, V 1 , Fadeev Dmitry S. 1 , Shults Elvira E. 1,2
Организации
1 (Данные Web of science) Russian Acad Sci, Novosibirsk Inst Organ Chem, Siberian Branch, Lab Med Chem, Lavrentyev Ave 9, Novosibirsk 630090, Russia
2 (Данные Web of science) Novosibirsk State Univ, Pirogova St 2, Novosibirsk 630090, Russia

Реферат: The design and the preparation of a small library of optically active polyazamacrocyclic compounds with a furan bridge, connected by (4-(methylaminomethyl)-1,2,3-triazole) rings with methylene, ethyloxyethyl or ethylethoxyethyl units from natural labdanoid lambertianic acid is reported. The synthesis of the key 15,16-bis((tert-butoxycarbonyl(prop-2-ynyl)amino)methyl)labda-8(9),13,15-labdatriene from the plant diterpenoid lambertianic acid is also described. CuAAC reaction of this compounds with various diazides in the presence of Cu(II)/sodium ascorbate in methylene chloride/water reaction medium led to the mentioned chiral macrocyclic compounds with a furan bridge binding Zn2+ ions in solution. [GRAPHICS]
Библиографическая ссылка: Brusentzeva O.I. , Kharitonov Y.V. , Fadeev D.S. , Shults E.E.
Synthesis and spectroscopic studies of furan-bridged polyazamacrocycles through 15,16-bis((prop-2-ynylamino)methyl)labdatriene transformations
Journal of Inclusion Phenomena and Macrocyclic Chemistry. 2020. V.96. N3-4. P.245-250. DOI: 10.1007/s10847-019-00965-z WOS Scopus OpenAlex
Даты:
Опубликована online: 22 нояб. 2019 г.
Опубликована в печати: 1 апр. 2020 г.
Идентификаторы БД:
Web of science: WOS:000498020800001
Scopus: 2-s2.0-85075348240
OpenAlex: W2990704197
Цитирование в БД:
БД Цитирований
Web of science 3
Scopus 4
OpenAlex 2
Альметрики: