Реферат: The approaches to the activation of perfluoroalkyl halides used as intermediates in the synthesis of partially fluorinated compounds are considered. The conditions for reactions of organic compounds with perfluoroalkyl iodides in the presence of reductants (Na2S2O4, HOCH2SO2Na), metals and metal salts, redox systems (Na2S2O8, ButOOH, Pb(OAc)4, H2O2-FeSO4, Ce(SO4)2) and transition metal complexes are described. The generation of perfluoroalkyl radicals by a single-electron transfer mechanism are discussed. The introduction of perfluoroalkyl groups into aromatic and unsaturated organic compounds and functionalisation of perfluoroalkyl iodides, particularly, their transformation into perfluoroalkanesulfinic and perfluoroalkanecarboxylic acids and aldehydes, are considered. The bibliography includes 442 references.

Библиографическая ссылка: Furin G.G.
Some new aspects in the application of perfluoroalkyl halides in the synthesis of fluorine-containing organic compounds
Russian Chemical Reviews. 2000. V.69. N6. P.491-522. DOI: 10.1070/RC2000v069n06ABEH000353 Scopus РИНЦ OpenAlex

Оригинальная: Furin G.G.
Novel aspects of perfluoroalkyl halide application to the synthesis of fluorine-containing organic compounds
Успехи химии/Uspekhi Khimii. 2000. V.69. N6. P.538-571. РИНЦ

Даты:

Опубликована в печати:	30 июн. 2000 г.
Опубликована online:	17 окт. 2007 г.

Идентификаторы БД:

Scopus:	2-s2.0-0003257086
РИНЦ:	13351866
OpenAlex:	W2081874183

Цитирование в БД:

БД	Цитирований
Scopus	40
РИНЦ	40
OpenAlex	46

Альметрики: